[(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate

Base Information

• Chemical Name: [(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate
• CAS No.: 1147124-85-3
• Molecular Formula: C₄₉H₃₉N₂O₅P₂Ru*F₆P
• Molecular Weight: 1043.84
• Mol file: 1147124-85-3.mol

Synonyms:[(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate

Chemical Property of [(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate

There total 3 articles about [(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + ammonium hexafluorophosphate + 2,2'-Bipyridine-4,4'-dicarboxylic acid (6813-38-3) → [(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate (1147124-85-3)

Guidance literature:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); 2,2'-Bipyridine-4,4'-dicarboxylic acid; In methanol; for 2h; Reflux;

ammonium hexafluorophosphate;

DOI:10.1016/j.molstruc.2019.06.005

Reference yield:

[Ru(PPh3)2(4,4'-dicarboxylic-2,2'-bipyridyl)(CO)(trifluoroacetate)]PF6 (1147124-83-1) → [(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate (1147124-85-3)

Guidance literature:

In ethanol; (N2); Ru complex was recrystd. from hot EtOH; elem. anal.;

DOI:10.1016/j.jorganchem.2008.11.048

Reference yield:

ammonium hexafluorophosphate + Ru(CO)2(PPh3)2(TFA)2 (56143-16-9,14655-17-5) + 2,2'-Bipyridine-4,4'-dicarboxylic acid (6813-38-3) → [(H)Ru(CO)(PPh3)2(4,4′-dicarboxy-2,2′-bipyridyl)] hexafluorophosphate (1147124-85-3) + [Ru(PPh3)2(4,4'-dicarboxylic-2,2'-bipyridyl)(CO)(trifluoroacetate)]PF6 (1147124-83-1)

Guidance literature:

In water; ethylene glycol; (N2); soln. of Ru complex and ligand in ethylene glycol was heated at 140°C for 72 h; aq. NH4PF6 was added; filtered; dissolved in CH2Cl2; chromd. (alumina, hexane/CH2Cl2, 1/1);

DOI:10.1016/j.jorganchem.2008.11.048

upstream raw materials:

Ru(CO)₂(PPh₃)₂(TFA)₂

2,2'-Bipyridine-4,4'-dicarboxylic acid

[Ru(PPh₃)2(4,4'-dicarboxylic-2,2'-bipyridyl)(CO)(trifluoroacetate)]PF₆

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

Refernces

• 1、 Sharmin, Ayesha,Darlington, Reuben C.,Hardcastle, Kenneth I.,Ravera, Mauro,Rosenberg, Edward,Alexander Ross. "Tuning photophysical properties with ancillary ligands in Ru(II) mono-diimine complexes". . p. 988 - 1000. Retrieved 2009/05/27.