C₄₂H₅₅NO₁₃

Base Information

• Chemical Name: C₄₂H₅₅NO₁₃
• CAS No.: 1369430-77-2
• Molecular Formula: C₄₂H₅₅NO₁₃
• Molecular Weight: 781.898
• Mol file: 1369430-77-2.mol

Synonyms:C₄₂H₅₅NO₁₃

Chemical Property of C₄₂H₅₅NO₁₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₂H₅₅NO₁₃

There total 21 articles about C₄₂H₅₅NO₁₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

u202fN-(2,2-dimethylbut-3-enoyl)-2-methylalanine (1240304-75-9) + (1S)-2,3,4,6-tetra-O-acetyl-1,5-anhydro-1-{5-[(4-bromo-2-methylphenyl)methyl]-2-methoxy-4-(propan-2-yl)phenyl}-D-glucitol (1240304-62-4) → C42H55NO13 (1369430-77-2)

Guidance literature:

With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine; In acetonitrile; at 120 ℃; for 0.333333h; Inert atmosphere; Microwave irradiation;

Reference yield:

3-isopropylhydroxybenzene (618-45-1) → C42H55NO13 (1369430-77-2)

Guidance literature:

Multi-step reaction with 14 steps

1.1: iodine; water; acetic acid; potassium iodate / 20 h / 20 °C

2.1: potassium carbonate / acetonitrile / 3.5 h / 40 °C

3.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere

3.2: 0.58 h / -78 °C / Inert atmosphere

4.1: methanesulfonic acid / 2 h / 20 °C

5.1: pyridine / 14 h / 20 °C

6.1: boron trifluoride diethyl etherate; triethylsilane / chloroform; acetonitrile / 1 h / 4 °C / Inert atmosphere

7.1: acetic acid; bromine / 20 °C

8.1: methanol; sodium methylate / 2 h / 20 °C

9.1: triethylamine / N,N-dimethyl-formamide / 4 - 20 °C / Inert atmosphere

10.1: n-butyllithium / tetrahydrofuran; hexane / 0.22 h / -78 °C / Inert atmosphere

10.2: 0.5 h / -78 °C / Inert atmosphere

11.1: methanesulfonic acid; methanol / 0.5 h / 20 °C

12.1: pyridine / 15 h / 20 °C

13.1: boron trifluoride diethyl etherate; triethylsilane / chloroform; acetonitrile / 0.5 h / 4 °C / Inert atmosphere

14.1: tris-(o-tolyl)phosphine; triethylamine; palladium diacetate / acetonitrile / 0.33 h / 120 °C / Inert atmosphere; Microwave irradiation

With pyridine; methanol; triethylsilane; potassium iodate; n-butyllithium; methanesulfonic acid; boron trifluoride diethyl etherate; water; bromine; iodine; sodium methylate; palladium diacetate; potassium carbonate; acetic acid; triethylamine; tris-(o-tolyl)phosphine; In tetrahydrofuran; hexane; chloroform; N,N-dimethyl-formamide; acetonitrile; 14.1: |Heck Reaction;

Reference yield:

1,5-dibromo-2-(methoxymethoxy)-4-(propan-2-yl)benzene (1240304-54-4) → C42H55NO13 (1369430-77-2)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.92 h / -80 - -76 °C / Inert atmosphere

1.2: 1.75 h / -80 - -76 °C / Inert atmosphere

2.1: potassium carbonate / N,N-dimethyl-formamide / 20 - 50 °C

3.1: tris-(o-tolyl)phosphine; triethylamine; palladium diacetate / acetonitrile / 0.33 h / 120 °C / Inert atmosphere; Microwave irradiation

With n-butyllithium; palladium diacetate; potassium carbonate; triethylamine; tris-(o-tolyl)phosphine; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; acetonitrile; 3.1: |Heck Reaction;

upstream raw materials:

2-iodo-5-(propan-2-yl)phenol

2,4-dibromo-5-isopropylphenol

1,5-dibromo-2-(methoxymethoxy)-4-(propan-2-yl)benzene

2,2-dimethyl-but-3-enoic acid

Refernces

• 1、 -. "4-ISOPROPYL-6-METHOXYPHENYL GLUCITOL COMPOUND". . . Retrieved 2013/07/05.