1-PYRENECARBOXYLIC ACID

Base Information

• Chemical Name: 1-PYRENECARBOXYLIC ACID
• CAS No.: 19694-02-1
• Molecular Formula: C17H10O2
• Molecular Weight: 246.265
• Hs Code.: 29163990
• Mol file: 19694-02-1.mol

Synonyms:3-Pyrenecarboxylicacid;

Chemical Property of 1-PYRENECARBOXYLIC ACID

Chemical Property:

• Vapor Pressure: 9.9E-11mmHg at 25°C
• Melting Point: 270-272 °C(lit.)
• Refractive Index: 1.871
• Boiling Point: 497.9 °C at 760 mmHg
• PKA: 3.49±0.30(Predicted)
• Flash Point: 218.4 °C
• PSA: 37.30000
• Density: 1.411g/cm³
• LogP: 4.28220
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: DMF: soluble

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Pyrenecarboxylic Acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: PCA can be used in the surface modification of graphene and carbon nanotubes (CNTs), which can further be used for a variety of electronic applications.

Technology Process of 1-PYRENECARBOXYLIC ACID

There total 2 articles about 1-PYRENECARBOXYLIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

pyrene (129-00-0) + malonic acid (141-82-2) → pyrene-1-aldehyde (3029-19-4) + Pyrene-1-carboxylic acid (19694-02-1) + α,α-diacetoxy-1-methylpyrene (123295-70-5)

Guidance literature:

With manganese triacetate; In acetic acid; for 0.0166667h; Heating;

DOI:10.1246/bcsj.62.545

Reference yield: 10.0%

pyrene (129-00-0) + malonic acid (141-82-2) + acetic acid (64-19-7,77671-22-8) → pyrene-1-aldehyde (3029-19-4) + Pyrene-1-carboxylic acid (19694-02-1) + α,α-diacetoxy-1-methylpyrene (123295-70-5)

Guidance literature:

With manganese triacetate; for 0.0166667h; Heating;

DOI:10.1246/bcsj.62.545

Reference yield: 91.2%

Pyrene-1-carboxylic acid (19694-02-1) + tert-butyl ((1R,2R)-2-aminocyclohexyl)carbamate (146504-07-6) → C28H30N2O3

Guidance literature:

With dmap; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃; for 72h;

DOI:10.1002/anie.202107842

upstream raw materials:

pyrene

malonic acid

acetic acid

Downstream raw materials:

4-nitrophenyl 1-pyrenecarboxylate

pyrene

carbon dioxide

3,10-bis(2-nitrobenzenesulfonyl)-6-[5-(1-pyrenecarbonyl)amino-1-pentanyl]-3,6,10,16-tetraazabicyclo[10.3.1]hexadeca-1⁽¹⁶⁾,12,14-triene

Refernces