Technology Process of 1-terphenyl-4-yl-3-phenylbenzene
There total 6 articles about 1-terphenyl-4-yl-3-phenylbenzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
4-bromo-p-terphenyl;
With
tetrakis(triphenylphosphine) palladium(0);
In
1,2-dimethoxyethane;
at 20 ℃;
for 0.166667h;
3-Biphenylboronic acid;
With
sodium carbonate;
In
1,2-dimethoxyethane;
for 24h;
Further stages.;
Heating;
DOI:10.1021/jp010869j
- Guidance literature:
-
With
copper;
at 270 ℃;
for 1h;
Further byproducts given;
DOI:10.1246/bcsj.53.2610
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -78 °C
1.2: tetrahydrofuran; hexane / -78 - 20 °C
1.3: 86 percent / aq. HCl / tetrahydrofuran; hexane / 1 h / 20 °C
2.1: tetrakis(triphenylphosphine)palladium(0) / 1,2-dimethoxy-ethane / 0.17 h / 20 °C
2.2: 80 percent / aq. Na2CO3 / 1,2-dimethoxy-ethane / 12 h / Heating
3.1: tetrakis(triphenylphosphine)palladium(0) / 1,2-dimethoxy-ethane / 0.17 h / 20 °C
3.2: 54 percent / aq. Na2CO3 / 1,2-dimethoxy-ethane / 24 h / Heating
With
tetrakis(triphenylphosphine) palladium(0); n-butyllithium;
In
tetrahydrofuran; 1,2-dimethoxyethane; hexane;
DOI:10.1021/jp010869j
