Bis(3-chlorophenyl)amine

Base Information

• Chemical Name: Bis(3-chlorophenyl)amine
• CAS No.: 32113-77-2
• Molecular Formula: C12H9 Cl2 N
• Molecular Weight: 238.116
• Hs Code.: 2921499090
• Mol file: 32113-77-2.mol

Synonyms:Diphenylamine,3,3'-dichloro- (8CI)

Chemical Property of Bis(3-chlorophenyl)amine

Chemical Property:

• Vapor Pressure: 8.11E-05mmHg at 25°C
• Refractive Index: 1.6300 (estimate)
• Boiling Point: 341.3°C at 760 mmHg
• Flash Point: 160.2°C
• PSA: 12.03000
• Density: 1.327g/cm³
• LogP: 4.81000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bis(3-chlorophenyl)amine

There total 4 articles about Bis(3-chlorophenyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1-bromo-3-chlorobenzene (108-37-2) + 3-chloro-aniline (108-42-9) → 3,3'-dichlorodiphenylamine (32113-77-2)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium t-butanolate; CyJohnPhos; In 1,4-dioxane; for 36h; Reflux;

DOI:10.1002/poc.3398

Reference yield:

N,N-Bis-(3-chloro-phenyl)-benzamide (77826-11-0) → 3,3'-dichlorodiphenylamine (32113-77-2) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With barium dihydroxide; cetyltrimethylammonim bromide; In water; at 65.5 ℃; Rate constant; Mechanism; absence of ctab, other reagent, other solvent;

DOI:10.1021/jo00330a029

Reference yield:

N-(3-chlorophenyl)benzimidoyl chloride (34918-77-9) + 3-monochlorophenol (108-43-0) → 3,3'-dichlorodiphenylamine (32113-77-2)

Guidance literature:

With diethyl ether; sodium ethanolate; und Erhitzen des erhaltenen N-<3-Chlor-phenyl>-benzimidsaeure-<3-chlor-phenylesters> auf 290grad und Erwaermen dann mit wss.-aethanol. Kalilauge auf Siedetemperatur;

DOI:10.1039/jr9310000294

upstream raw materials:

N-(3-chlorophenyl)benzimidoyl chloride

3-monochlorophenol

N,N-Bis-(3-chloro-phenyl)-benzamide

3-chloro-aniline

Downstream raw materials:

bis-(3-chloro-phenyl)-[2-(1-methyl-[2]piperidyl)-ethyl]-amine

Refernces

• 1、 Broxton, Trevor J.,Fernando, Denise R.,Rowe, Jeffrey E.. "Micellar Catalysis of the Basic Hydrolysis of Amides. 4. Substituted N,N-Diphenylbenzamides". . p. 3522 - 3525. Retrieved 2007/10/02.