deuterophosphorous acid

Base Information

• Chemical Name: deuterophosphorous acid
• CAS No.: 57583-55-8
• Molecular Formula: H₃O₃P
• Molecular Weight: 84.972
• Mol file: 57583-55-8.mol

Synonyms:deuterophosphorous acid

Chemical Property of deuterophosphorous acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of deuterophosphorous acid

There total 3 articles about deuterophosphorous acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosphorous (12185-10-3) + water-d2 (7789-20-0) + dibenzoyl peroxide (94-36-0) → trideutero hypophosphorous acid (57583-56-9) + deuterophosphorous acid (57583-55-8) + [D3]phosphoric acid (14335-33-2)

Guidance literature:

In water-d2; toluene; Ar, P4 (or soln. of P4 in toluene) added in small portions, heated to 60-60°C, stirred for 0.5-4 h; not isolated, detected by NMR; Kinetics;

DOI:10.1016/j.molcata.2006.11.046

Reference yield:

tert.-butylhydroperoxide (75-91-2) + phosphorous (12185-10-3) + water-d2 (7789-20-0) → trideutero hypophosphorous acid (57583-56-9) + deuterophosphorous acid (57583-55-8) + [D3]phosphoric acid (14335-33-2)

Guidance literature:

In water-d2; toluene; Ar, P4 (or soln. of P4 in toluene) added in small portions, heated to 25-60°C, stirred for 0.5-4 h; not isolated, detected by NMR; Kinetics;

DOI:10.1016/j.molcata.2006.11.046

Reference yield:

phosphorous (12185-10-3) + dihydrogen peroxide (7722-84-1) + water-d2 (7789-20-0) → trideutero hypophosphorous acid (57583-56-9) + deuterophosphorous acid (57583-55-8) + [D3]phosphoric acid (14335-33-2)

Guidance literature:

In water-d2; Ar, P4 added in small portions, heated to 25-90°C, stirred for 0.5-4 h; not isolated, detected by NMR; Kinetics;

DOI:10.1016/j.molcata.2006.11.046

upstream raw materials:

tert.-butylhydroperoxide

phosphorous

water-d2

dihydrogen peroxide

Downstream raw materials:

[D₃]phosphoric acid

Refernces