Bismuth(III) trifluoromethanesulfonate

Base Information

• Chemical Name: Bismuth(III) trifluoromethanesulfonate
• CAS No.: 88189-03-1
• Molecular Formula: C3BiF9O9S3
• Molecular Weight: 674.2
• Hs Code.: 29049090
• European Community (EC) Number: 628-926-6
• UNII: 51KD8E1741
• DSSTox Substance ID: DTXSID70432758
• Nikkaji Number: J1.017.150D
• Mol file: 88189-03-1.mol

Synonyms:Bi(OTf)3;bismuth triflate;bismuth trifluoromethanesulfonate;bismuth(III) triflate

Chemical Property of Bismuth(III) trifluoromethanesulfonate

Chemical Property:

• Appearance/Colour: White powder
• Vapor Pressure: 1.14mmHg at 25°C
• Melting Point: 300 °C
• Boiling Point: 162 °C at 760 mmHg
• PSA: 196.74000
• LogP: 3.39660
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Solubility.: Soluble in organics acetonitrile, dioxane, dimethyl formamide an
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 18
• Rotatable Bond Count: 0
• Exact Mass: 655.83647
• Heavy Atom Count: 25
• Complexity: 145

Purity/Quality:

99%+, ^*data from raw suppliers

Bismuth(III)Trifluoromethanesulfonate(3:1) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Bi+3]
• Uses: Bismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions. Catalyst for organic syntheses. Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions. Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.