7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate

Base Information

• Chemical Name: 7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate
• CAS No.: 82135-27-1
• Molecular Formula: CHF₃O₃S*C₂₇H₂₁N
• Molecular Weight: 509.549
• Mol file: 82135-27-1.mol

Synonyms:7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate

Chemical Property of 7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate

There total 2 articles about 7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

1-benzyl-5,6,8,9-tetrahydro-7-phenyldibenzoacridinium triflouromethanesulphonate (76017-71-5) → 4-chlorophenyl(phenyl)methane (831-81-2) + (o-benzyl)chlorobenzene (29921-41-3) + 1-benzyl-3-chlorobenzene (27798-38-5) + 7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate (82135-27-1)

Guidance literature:

In chlorobenzene; for 4h; Heating;

DOI:10.1039/P29860001331

Reference yield:

N-n-octyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate (73377-30-7) + phenol (108-95-2,27073-41-2) → octyloxybenzene (1818-07-1) + 2-(1-Methylheptyl)phenol (18626-98-7) + p-(4-octyl)phenol (3307-01-5) + o-(4-octyl)phenol (37631-10-0) + 2-(3-octyl)phenol (17404-44-3) + 7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate (82135-27-1)

Guidance literature:

at 160 ℃; for 84h; Product distribution; also N-dodecylacridinium triflate;

DOI:10.1021/jo00139a025

Reference yield: 63.0%

2-aminoacetonitrile hydrochloride (6011-14-9) + 7-phenyl-5,6,8,9-tetrahydrodibenzoxanthylium trifluoromethanesulphonate (82135-27-1) → 14-cyanomethyl-7-phenyl-5,6,8,9-tetrahydrodibenzoacridinium trifluoromethanesulphonate (86445-53-6)

Guidance literature:

With triethylamine; In dichloromethane; at 25 ℃; for 5h;

upstream raw materials:

1-benzyl-5,6,8,9-tetrahydro-7-phenyldibenzoacridinium triflouromethanesulphonate

N-n-octyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate

phenol

Downstream raw materials:

14-cyanomethyl-7-phenyl-5,6,8,9-tetrahydrodibenzoacridinium trifluoromethanesulphonate

Refernces

• 1、 Katritzky, Alan R.,El-Mowafy, Azzahra M.. "Solvolysis of N-n-Alkylacridiniums in Phenol and Carboxylic Acids. Primary Carbonium Ions as Possible Intermediates". . p. 3511 - 3517. Retrieved 2007/10/02.