(2-nitrobenzyl)triphenylphosphonium

Base Information

• Chemical Name: (2-nitrobenzyl)triphenylphosphonium
• CAS No.: 62173-41-5
• Molecular Formula: C₂₅H₂₁NO₂P
• Molecular Weight: 398.421
• Mol file: 62173-41-5.mol

Synonyms:(2-nitrobenzyl)triphenylphosphonium

Chemical Property of (2-nitrobenzyl)triphenylphosphonium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-nitrobenzyl)triphenylphosphonium

There total 3 articles about (2-nitrobenzyl)triphenylphosphonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(2-boronobenzyl)triphenylphosphonium (1247338-12-0) → (2-hydroxybenzyl)triphenylphosphonium + (2-nitrobenzyl)triphenylphosphonium (62173-41-5)

Guidance literature:

With Peroxynitrite anion; Kinetics;

DOI:10.1021/tx300499c

Reference yield:

(2-boronobenzyl)triphenylphosphonium (1247338-12-0) → (2-hydroxybenzyl)triphenylphosphonium + benzyltriphenylphosphonium cation (15853-35-7) + (2-nitrobenzyl)triphenylphosphonium (62173-41-5) + 9,10-Dihydro-9,9-diphenyl-9-phosphoniaphenanthren

Guidance literature:

With Peroxynitrite anion; Mechanism;

DOI:10.1074/jbc.M115.702787

Reference yield:

triphenylphosphine (603-35-0) + 2-nitrophenylmethyl bromide (3958-60-9) → (2-nitrobenzyl)triphenylphosphonium (62173-41-5)

Guidance literature:

In toluene; at 100 ℃; for 12h;

DOI:10.1002/anie.201810870

upstream raw materials:

(2-boronobenzyl)triphenylphosphonium

triphenylphosphine

2-nitrophenylmethyl bromide

Refernces

• 1、 Romero, Kevin J.,Galliher, Matthew S.,Raycroft, Mark A. R.,Chauvin, Jean-Philippe R.,Bosque, Irene,Pratt, Derek A.,Stephenson, Corey R. J.. "Electrochemical Dimerization of Phenylpropenoids and the Surprising Antioxidant Activity of the Resultant Quinone Methide Dimers". supporting information. p. 17125 - 17129. Retrieved 2018/12/04.