tri([1,1′-biphenyl]-4-yl)bismuth

Base Information

• Chemical Name: tri([1,1′-biphenyl]-4-yl)bismuth
• CAS No.: 29712-10-5
• Molecular Formula: C₃₆H₂₇Bi
• Molecular Weight: 668.591
• Mol file: 29712-10-5.mol

Synonyms:tri([1,1′-biphenyl]-4-yl)bismuth

Chemical Property of tri([1,1′-biphenyl]-4-yl)bismuth

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of tri([1,1′-biphenyl]-4-yl)bismuth

There total 3 articles about tri([1,1′-biphenyl]-4-yl)bismuth which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

bismuth(III) chloride + 4-bromo-1,1'-biphenyl (92-66-0) → tri([1,1′-biphenyl]-4-yl)bismuth (29712-10-5)

Guidance literature:

4-bromo-1,1'-biphenyl; With iodine; magnesium; In tetrahydrofuran; at 65 ℃; for 2h; Schlenk technique; Sealed tube; Inert atmosphere;

bismuth(III) chloride; In tetrahydrofuran; at 0 - 65 ℃; for 4h;

DOI:10.1021/acs.organomet.1c00339

Reference yield: 50.0%

4-biphenylylmagnesium bromide (3315-91-1) + bismuth(III) chloride (7787-60-2) → tri([1,1′-biphenyl]-4-yl)bismuth (29712-10-5)

Guidance literature:

In diethyl ether; 15 h; decanting, extracting the ppt. with warm C2H5OH-CHCl3;

DOI:10.1021/ja01300a507

Reference yield:

4-bromo-1,1'-biphenyl (92-66-0) → p-quaterphenyl (135-70-6) + tri([1,1′-biphenyl]-4-yl)bismuth (29712-10-5)

Guidance literature:

With diethyl ether; magnesium; anschliessendes Behandeln mit Wismut(III)-chlorid;

DOI:10.1021/ja01300a507

upstream raw materials:

4-bromo-1,1'-biphenyl

4-biphenylylmagnesium bromide

bismuth(III) chloride

Downstream raw materials:

(p-C₆H₅C₆H₄)2BiCl

(1,1′-biphenyl)-4-yldiphenylphosphine oxide

(4-biphenylyl)-p-tolyl sulfone

Refernces