p,p'-diiodoazoxybenzene

Base Information

• Chemical Name: p,p'-diiodoazoxybenzene
• CAS No.: 603121-28-4
• Molecular Formula: C₁₂H₈I₂N₂O
• Molecular Weight: 450.017
• Mol file: 603121-28-4.mol

Synonyms:p,p'-diiodoazoxybenzene

Chemical Property of p,p'-diiodoazoxybenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p,p'-diiodoazoxybenzene

There total 13 articles about p,p'-diiodoazoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

p-nitrobenzene iodide (636-98-6) + potassium isopropoxide (6831-82-9) → nitrobenzene (98-95-3,26969-40-4) + p,p'-diiodoazoxybenzene (603121-28-4)

Guidance literature:

In isopropyl alcohol; at 75 ℃; Mechanism; Product distribution; Rate constant; also with the K⁺ complexing 18-crown-6 ether under anaerobic and aerobic conditions;

DOI:10.1021/jo00298a044

Reference yield: 95.0%

p-aminoiodobenzene (540-37-4) → p,p'-diiodoazoxybenzene (603121-28-4)

Guidance literature:

With trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane; In ethanol; at 20 ℃; for 0.166667h; Sonication; Green chemistry;

DOI:10.1007/s13738-013-0328-z

Reference yield: 82.0%

p-nitrobenzene iodide (636-98-6) → p,p'-diiodoazoxybenzene (603121-28-4)

Guidance literature:

With oxygen; ammonium chloride; zinc; In [bmim][BF₄]; water; at 20 ℃; for 16h;

DOI:10.1016/j.tetlet.2009.02.122

upstream raw materials:

p-nitrobenzene iodide

sodium butanolate

benzene

potassium isopropoxide

Downstream raw materials:

C₁₂H₈I₂N₂O

bis-(4-iodo-phenyl)-diazene

hydrazo(4-iodobenzene)

Refernces

• 1、 Sadatnabi, Ali,Mohamadighader, Niloofar,Nematollahi, Davood. "Convergent Paired Electrochemical Synthesis of Azoxy and Azo Compounds: An Insight into the Reaction Mechanism". supporting information. p. 6488 - 6493. Retrieved 2021/08/23.
• 2、 Chen, Zhichao,Qiu, Yatao,Wu, Xiaoxing,Ni, Yong,Shen, Li,Wu, Jun,Jiang, Sheng. "Highly selective reduction of nitrobenzenes to azoxybenzenes with a copper catalyst". supporting information. p. 1382 - 1384. Retrieved 2018/03/06.