dioxovanadium(1+)

Base Information

• Chemical Name: dioxovanadium(1+)
• CAS No.: 18252-79-4
• Molecular Formula: O₂V
• Molecular Weight: 82.9403
• Mol file: 18252-79-4.mol

Synonyms:Vanadium(1+),dioxo-, ion (8CI); Dioxovanadium(+); Dioxovanadium(1+); Vanadium dioxide(1+);Vanadyl (VO2+); Vanadyl ion (VO2+); Vanadyl ion (VO21+)

Chemical Property of dioxovanadium(1+)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dioxovanadium(1+)

There total 12 articles about dioxovanadium(1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dihydrogendecavanadate (4-) ion + hydrogen cation → water (7732-18-5) + vanadium(V) ion (18252-79-4)

Guidance literature:

In water; equilibrium;;

DOI:10.1021/ja01512a010

Reference yield:

oxovanadium(IV) sulfate + potassium iodate (7758-05-6) → iodide (14362-44-8,20461-54-5,69239-56-1) + vanadium(V) ion (18252-79-4)

Guidance literature:

With perchloric acid; sodium perchlorate; acetic acid; osmium(VIII) oxide; In perchloric acid; VOSO4 oxidized with KIO3 catalyzed by OsO4 in aq. HClO4-aq. CH3CO2H media at 50-70°C, ionic strength 0.06-0.151 mol/l (NaClO4); followed iodometrically; Kinetics;

DOI:10.1246/bcsj.55.3617

Reference yield:

vanadyl (20644-97-7) → vanadium(V) ion (18252-79-4)

Guidance literature:

With cerium(IV); In not given; byproducts: Ce(3+); oxydation in acidic solution in presence of Ce(4+) (as coordination compound) with formation of Ce(3+) (as coordination compound);;

DOI:10.1021/ac50120a006

upstream raw materials:

nitric acid

potassium iodate

caesium fluoroxysulphate

tert.-butylhydroperoxide

Downstream raw materials:

water

vanadyl

Refernces

• 1、 Hoch, Martin,Rehder, Dieter,Weidemann, Carola. "". . p. L5 - L8. Retrieved 1984.
• 2、 Newman, L.,Quinlan, K. P.. "". . p. 547 - 549. Retrieved 1959.
• 3、 Liu, Yongguang,Jiang, Yingqiao,Lv, Yanrong,He, Zhangxing,Dai, Lei,Wang, Ling. "Synergistic catalysis of sno2/reduced graphene oxide for vo2+/vo2+ and v2+/v3+ redox reactions". . . Retrieved 2021/08/30.
• 4、 Ma, Rong,Bakac, Andreja,Espenson, James H.. "Kinetics of oxidation of vanadium(IV) by alkyl hydroperoxides in acidic, aqueous solution". . p. 1925 - 1930. Retrieved 2008/10/08.