Peroxydicarbonic acid, bis[2-(2-phenoxyethoxy)ethyl] ester

Base Information

• Chemical Name: Peroxydicarbonic acid, bis[2-(2-phenoxyethoxy)ethyl] ester
• CAS No.: 31603-33-5
• Molecular Formula: C₂₂H₂₆O₁₀
• Molecular Weight: 450.442
• DSSTox Substance ID: DTXSID501193873
• Mol file: 31603-33-5.mol

Synonyms:Peroxydicarbonic acid, bis[2-(2-phenoxyethoxy)ethyl] ester;DTXSID501193873;31603-33-5

Chemical Property of Peroxydicarbonic acid, bis[2-(2-phenoxyethoxy)ethyl] ester

Chemical Property:

• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 19
• Exact Mass: 450.15259702
• Heavy Atom Count: 32
• Complexity: 445

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OCCOCCOC(=O)OOC(=O)OCCOCCOC2=CC=CC=C2

Technology Process of Peroxydicarbonic acid, bis[2-(2-phenoxyethoxy)ethyl] ester

There total 3 articles about Peroxydicarbonic acid, bis[2-(2-phenoxyethoxy)ethyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

phenoxyethoxyethyl chloroformate (81731-00-2) → bis(phenoxyethoxyethyl) peroxydicarbonate (31603-33-5)

Guidance literature:

With sodium peroxide; In diethyl ether; at 0 - 5 ℃; for 0.5h;

Reference yield:

2-(2-phenoxyethoxy)ethanol (104-68-7,9004-78-8) → bis(phenoxyethoxyethyl) peroxydicarbonate (31603-33-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 99 percent / 3 h / 3 - 5 °C

2: 62 percent / aq. Na₂O₂ / diethyl ether / 0.5 h / 0 - 5 °C

With sodium peroxide; In diethyl ether;

Reference yield:

→ bis(phenoxyethoxyethyl) peroxydicarbonate (31603-33-5)

Guidance literature:

entspr.Chlorformiat, H2O2;

upstream raw materials:

phenoxyethoxyethyl chloroformate

2-(2-phenoxyethoxy)ethanol

Downstream raw materials:

carbon dioxide

β,β'-Bis(phenoxyethyl)ether

2-(2-phenoxyethoxy)ethanol

Glycolaldehyde

Refernces