(naphthalen-3-yl)(2-nitrophenyl)sulfane

Base Information

• Chemical Name: (naphthalen-3-yl)(2-nitrophenyl)sulfane
• CAS No.: 294856-51-2
• Molecular Formula: C₁₆H₁₁NO₂S
• Molecular Weight: 281.335
• Mol file: 294856-51-2.mol

Synonyms:(naphthalen-3-yl)(2-nitrophenyl)sulfane

Chemical Property of (naphthalen-3-yl)(2-nitrophenyl)sulfane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (naphthalen-3-yl)(2-nitrophenyl)sulfane

There total 6 articles about (naphthalen-3-yl)(2-nitrophenyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ortho-nitrofluorobenzene (1493-27-2,127723-77-7) + 2-Naphthalenethiol (91-60-1) → (naphthalen-3-yl)(2-nitrophenyl)sulfane (294856-51-2)

Guidance literature:

With sodium t-butanolate; In water; at 20 ℃; for 3h;

Reference yield: 89.0%

4-Fluoronitrobenzene (350-46-9,178603-76-4) + 2-Naphthalenethiol (91-60-1) → (naphthalen-3-yl)(2-nitrophenyl)sulfane (294856-51-2)

Guidance literature:

With potassium hydroxide; hydroxypropyl methylcellulose; In water; at 20 ℃;

DOI:10.1039/d1gc00128k

Reference yield: 88.0%

2-nitrophenyl bromide (577-19-5) + 2-Naphthalenethiol (91-60-1) → (naphthalen-3-yl)(2-nitrophenyl)sulfane (294856-51-2)

Guidance literature:

aluminum oxide; cesium fluoride; at 110 ℃; for 0.0666667h; microwave irradiation;

DOI:10.1039/b001824o

upstream raw materials:

2-Chloronitrobenzene

2-Naphthalenethiol

2-nitrophenyl bromide

ortho-nitrobenzoic acid

Downstream raw materials:

2-(naphthalene-2-sulfonyl)-aniline

2-((2-nitrophenyl)sulfonyl)naphthalene

Refernces

• 1、 -. "ORGANIC REACTIONS CARRIED OUT IN AQUEOUS SOLUTION IN THE PRESENCE OF A HYDROXYALKYL(ALKYL)CELLULOSE OR AN ALKYLCELLULOSE". Page/Page column 249; 250; 251. . Retrieved 2017/08/21.
• 2、 Isley, Nicholas A.,Linstadt, Roscoe T. H.,Kelly, Sean M.,Gallou, Fabrice,Lipshutz, Bruce H.. "Nucleophilic Aromatic Substitution Reactions in Water Enabled by Micellar Catalysis". supporting information. p. 4734 - 4737. Retrieved 2015/10/12.