3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane

Base Information

• Chemical Name: 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane
• CAS No.: 136213-18-8
• Molecular Formula: C₁₉H₃₅NSi₂
• Molecular Weight: 333.665
• Mol file: 136213-18-8.mol

Synonyms:3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane

Chemical Property of 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane

There total 1 articles about 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

1,1,1,2,2,2-hexamethyldisilane (1450-14-2) + 2,6-diisopropylphenylisocyanide (2008-61-9) → 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane (136213-18-8)

Guidance literature:

With palladium diacetate; In toluene; for 20h; Heating;

DOI:10.1021/ja00023a043

Reference yield: 70.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + lithium aluminium tetrahydride (16853-85-3) + 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane (136213-18-8) → ((C4H8O)2LiH3Al(N(C6H3(CH(CH3)2)2)CH(Si(CH3)3)2))2 (1011530-91-8)

Guidance literature:

In tetrahydrofuran; under Ar or N2; soln. of ligand in THF added to LiAlH4 in THF at room temp.; refluxed for 10 h; solvent removed under vac.; washed with n-hexane; recrystd. from tolueneat -40°C;

DOI:10.1021/om700972a

Reference yield:

3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane (136213-18-8) → 2,6-diisopropylbenzenamine (24544-04-5) + 2,6-diisopropylphenylisocyanide (2008-61-9) + 2,6-diisopropylphenyl isocyanate (28178-42-9) + 2,6-di(isopropyl)-N-methyleneaniline (60090-48-4)

Guidance literature:

With tetrachloromethane; In benzene-d6; at 20 ℃; for 2h; Product distribution; Photolysis;

DOI:10.1021/jo991443s

upstream raw materials:

1,1,1,2,2,2-hexamethyldisilane

2,6-diisopropylphenylisocyanide

Downstream raw materials:

2,6-diisopropylbenzenamine

2,6-diisopropylphenylisocyanide

2,6-diisopropylphenyl isocyanate

2,6-di(isopropyl)-N-methyleneaniline

Refernces

• 1、 Ito, Yoshihiko,Suginome, Michinori,Matsuura, Takaharu,Murakami, Masahiro. "Palladium-catalyzed insertion of isocyanides into the silicon-silicon linkages of oligosilanes". . p. 8899 - 8908. Retrieved 2007/10/02.