hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)

Base Information

• Chemical Name: hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)
• CAS No.: 98716-00-8
• Molecular Formula: C₄₄H₂₁F₈FeN₄O
• Molecular Weight: 829.511
• Mol file: 98716-00-8.mol

Synonyms:hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)

Chemical Property of hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)

There total 10 articles about hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tetrakis(2,6-difluorophenyl)porphyrinate(2-)iron(II) (162257-76-3) + 2,4-di-tert-Butylphenol (96-76-4) → hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III) (98716-00-8) + 2,4-di-tert-butyl-6-nitrophenol (20039-94-5)

Guidance literature:

tetrakis(2,6-difluorophenyl)porphyrinate^(2-)iron(II); With tetrahydrofuran; oxygen; at -80 ℃; Inert atmosphere;

2,4-di-tert-Butylphenol; With nitrogen(II) oxide; In tetrahydrofuran; at -80 - 20 ℃; Inert atmosphere;

DOI:10.1021/ja904832j

Reference yield: 60.0%

{(tetrakis(2,6-difluorophenyl)porphyrin)iron(III)-O2(2-)-copper(II)(tris(2-pyridylmethyl)amine)}(1+) → hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III) (98716-00-8) + {(copper(II)(tris(2-pyridylmethyl)amine))2(CO3)}(2+) (118458-34-7)

Guidance literature:

With CO₂; In acetonitrile; under Ar;;

Reference yield: 54.0%

[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride (99038-25-2,221335-24-6) → hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III) (98716-00-8)

Guidance literature:

With NaOH; In sodium hydroxide; dichloromethane; aq. NaOH; the starting complex in CH2Cl2 is stirred with aq. NaOH for 3-4 h; the organic layer is separated, heptane is added, elem. anal.;

DOI:10.1021/ja00090a023

upstream raw materials:

oxygen

[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride

9,10-dihydro-10-methylacridine

xanthene

Refernces

• 1、 Schopfer, Mark P.,Mondal, Biplab,Lee, Dong-Heon,Sarjeant, Amy A. N.,Karlin, Kenneth D.. "Heme/O2/?NO nitric oxide dioxygenase (NOD) reactivity: Phenolic nitration via a putative heme-peroxynitrite intermediate". supporting information; experimental part. p. 11304 - 11305. Retrieved 2011/03/19.
• 2、 Chufan, Eduardo E.,Verani, Claudio N.,Puiu, Simona C.,Rentschler, Eva,Schatzschneider, Ulrich,Incarvito, Christopher,Rheingold, Arnold L.,Karlin, Kenneth D.. "Generation and characterization of [(P)M-(X)-CO(TMPA)]n+ assemblies; P = porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O22-, and TMPA = tris(2-pyridylmethyl)amine". . p. 3017 - 3026. Retrieved 2008/10/09.