di-μ-chloro-bis[chloro(η⁵-pentamethylcyclopentadienyl)cobalt]

Base Information

• Chemical Name: di-μ-chloro-bis[chloro(η⁵-pentamethylcyclopentadienyl)cobalt]
• CAS No.: 82595-77-5
• Molecular Formula: C₂₀H₃₀Cl₄Co₂
• Molecular Weight: 530.257
• Mol file: 82595-77-5.mol

Synonyms:di-μ-chloro-bis[chloro(η⁵-pentamethylcyclopentadienyl)cobalt]

Chemical Property of di-μ-chloro-bis[chloro(η⁵-pentamethylcyclopentadienyl)cobalt]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di-μ-chloro-bis[chloro(η⁵-pentamethylcyclopentadienyl)cobalt]

There total 1 articles about di-μ-chloro-bis[chloro(η⁵-pentamethylcyclopentadienyl)cobalt] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Cp*CoCl]2 (125781-48-8) + diphenyl acetylene (501-65-5) → di-μ-chloro-bis[chloro(η5-pentamethylcyclopentadienyl)cobalt] (82595-77-5) + [(η5-C5Me5)Co(1,2,3,4-tetraphenyl-η4-cyclobutadiene)]

Guidance literature:

at or below room temp.;

Reference yield: 82.0%

di-μ-chloro-bis[chloro(η5-pentamethylcyclopentadienyl)cobalt] (82595-77-5) + C18H16NOP → C28H30CoNOP

Guidance literature:

C₁₈H₁₆NOP; With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

di-μ-chloro-bis[chloro(η⁵-pentamethylcyclopentadienyl)cobalt]; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/acs.organomet.9b00486

Reference yield: 75.0%

di-μ-chloro-bis[chloro(η5-pentamethylcyclopentadienyl)cobalt] (82595-77-5) + tetraphenylarsonium chloride (507-28-8,14842-08-1) → Tetraphenylarsonium-trinitro(pentamethylcyclopentadienyl)cobaltat

Guidance literature:

With sodium nitrite; In water; extn. (methylene chloride) of cobalt complex and NaNO2 soln., addition AsPh4Cl to the water soln.; extn. (methylene chloride), evapn., pptn. (pentane), elem. anal.;

upstream raw materials:

[Cp*CoCl]₂

diphenyl acetylene