nitrosylsulfuric acid fluoride

Base Information

• Chemical Name: nitrosylsulfuric acid fluoride
• CAS No.: 1087413-67-9
• Molecular Formula: FNO₃S
• Molecular Weight: 113.069
• Mol file: 1087413-67-9.mol

Synonyms:nitrosylsulfuric acid fluoride

Chemical Property of nitrosylsulfuric acid fluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of nitrosylsulfuric acid fluoride

There total 2 articles about nitrosylsulfuric acid fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fluorosulfonyl azide (13537-39-8) + nitrogen(II) oxide (10102-43-9) → nitrosylsulfuric acid fluoride (1087413-67-9) + fluorosulfonyl radical (12159-89-6) + fluoro sulfonyl nitrene + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) + dinitrogen monoxide (10024-97-2)

Guidance literature:

Pyrolysis; Inert atmosphere;

DOI:10.1021/ja312073w

Reference yield:

phosphorous + selenium(IV) fluoride (13465-66-2,271781-78-3) → selenium(IV) oxide (7446-08-4) + trifluorophosphoric acid (13478-20-1) + nitrosylsulfuric acid fluoride (1087413-67-9) + trifluorophosphane (7783-55-3)

Guidance literature:

DOI:10.1039/JR9280001603

Reference yield:

nitrosylsulfuric acid fluoride (1087413-67-9) + phosphorus trichloride (7719-12-2,52843-90-0) → trifluorophosphane (7783-55-3)

Guidance literature:

In not given; byproducts: NO(PF6); react. pf PCl3 with NOSO2F;;

upstream raw materials:

selenium(IV) fluoride

fluorosulfonyl azide

nitrogen(II) oxide

Downstream raw materials:

nitrosyl hexafluorophosphate

sulfur dioxide

nitrogen(II) oxide

nitrosylchloride

Refernces

• 1、 Zeng, Xiaoqing,Beckers, Helmut,Willner, Helge. "Thermally persistent fluorosulfonyl nitrene and unexpected formation of the fluorosulfonyl radical". . p. 2096 - 2099. Retrieved 2013/04/23.