2,4-di-tert-butyl muconolactone

Base Information

• Chemical Name: 2,4-di-tert-butyl muconolactone
• CAS No.: 22802-86-4
• Molecular Formula: C₁₄H₂₂O₄
• Molecular Weight: 254.326
• Mol file: 22802-86-4.mol

Synonyms:2,4-di-tert-butyl muconolactone

Chemical Property of 2,4-di-tert-butyl muconolactone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4-di-tert-butyl muconolactone

There total 26 articles about 2,4-di-tert-butyl muconolactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2,4-di-tert-Butylphenol (96-76-4) → 2,4-di-tert-butyl muconolactone (22802-86-4) + 3,5-di-tert-butyl-o-benzoquinone (3383-21-9)

Guidance literature:

With 2,2'-dinitro-4,4'-di(trifluoromethyl)diphenyl diselenide; dihydrogen peroxide; In water; tert-butyl alcohol; at 80 ℃; for 20h;

DOI:10.1080/00397910802369687

Reference yield: 61.0%

3,5-Di-tert-butylcatechol (1020-31-1,122983-47-5,881376-69-8) → 3,5-di-tert-butyl-muconic acid anhydride (24289-60-9) + 2,4-di-tert-butyl muconolactone (22802-86-4) + 3-tert-butylfuran-2,5-dione (18261-07-9) + 3,5-di-tert-butyl-o-benzoquinone (3383-21-9)

Guidance literature:

With water; oxygen; iron(III) chloride; In tetrahydrofuran; at 25 ℃; for 24h; under 760 Torr;

DOI:10.1246/cl.1987.719

Reference yield: 52.0%

3,5-Di-tert-butylcatechol (1020-31-1,122983-47-5,881376-69-8) → 2,4-di-tert-butyl muconolactone (22802-86-4) + 3-tert-butylfuran-2,5-dione (18261-07-9) + 3,5-di-tert-butyl-o-benzoquinone (3383-21-9) + 3,5-di-tert-butyl-5-(formyl)-2-furanone (87221-87-2)

Guidance literature:

With pyridine; 1,1'-bipyridyl; oxygen; iron(III) chloride; In tetrahydrofuran; at 25 ℃; for 24h; under 760 Torr; Further byproducts given;

DOI:10.1246/cl.1987.719

upstream raw materials:

methanol

3,5-di-tert-butyl-o-benzoquinone

3,5-Di-tert-butylcatechol

2,4-di-tert-Butylphenol

Refernces

• 1、 Das, Oindrila,Chatterjee, Sayanti,Paine, Tapan Kanti. "Iron and cobalt complexes of 4,4,9,9-tetramethyl-5,8-diazadodecane-2,11- dione dioxime ligand: Synthesis, characterization and reactivity studies". . p. 839 - 846. Retrieved 2011.
• 2、 Hu, Xue-Feng,Wu, Lei. "Oxidation of 3,5-di-tert-butylcatechol in the presence of V-polyoxometalate". . p. 211 - 215. Retrieved 2012.
• 3、 Chowdhury, Biswajit,Maji, Milan,Biswas, Bhaskar. "Catalytic aspects of a copper(II) complex: biological oxidase to oxygenase activity". . p. 1627 - 1637. Retrieved 2017/11/03.
• 4、 Metzinger, Ramona,Demeshko, Serhiy,Limberg, Christian. "A novel pentadentate redox-active ligand and its iron(III) complexes: Electronic structures and O2 reactivity". . p. 4721 - 4735. Retrieved 2014/05/06.