perfluoromethacryloyl fluoride

Base Information

• Chemical Name: perfluoromethacryloyl fluoride
• CAS No.: 684-36-6
• Molecular Formula: C₄F₆O
• Molecular Weight: 178.034
• Mol file: 684-36-6.mol

Synonyms:perfluoromethacryloyl fluoride

Chemical Property of perfluoromethacryloyl fluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of perfluoromethacryloyl fluoride

There total 3 articles about perfluoromethacryloyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

1,3,3,3-tetrafluoro-1-methoxy-2-trifluoromethyl-propene (360-53-2) → Methyl fluoride (593-53-3) + perfluoromethacryloyl fluoride (684-36-6) + bis(trifluoromethyl)ketene (684-22-0)

Guidance literature:

antimony pentafluoride; In neat (no solvent); Ambient temperature;

DOI:10.1021/jo00195a025

Reference yield:

tetraethylammonium perfluoroisobutenolate → Methyl fluoride (593-53-3) + perfluoromethacryloyl fluoride (684-36-6)

Guidance literature:

With antimony pentafluoride; at 0 ℃; Product distribution; Mechanism; various fluorinated vinyl ethers;

DOI:10.1007/BF00956597

Reference yield:

1,3,3,3-tetrafluoro-1-methoxy-2-trifluoromethyl-propene (360-53-2) → Methyl fluoride (593-53-3) + perfluoromethacryloyl fluoride (684-36-6)

Guidance literature:

Product distribution; Mechanism; unspecified electrophilic and nucleophilic (?) reagents;

DOI:10.1016/S0022-1139(00)83413-2

upstream raw materials:

1,3,3,3-tetrafluoro-1-methoxy-2-trifluoromethyl-propene

Downstream raw materials:

methyl 2-(trifluoromethyl)-3,3,3-trifluoropropionate

3,3,3-trifluoro-2-trifluoromethyl-propionyl fluoride

3,5-Diphenyl-6,6-bis-trifluoromethyl-cyclohexa-2,4-dienone

2,2,4-Trifluoro-3-(trifluoromethyl)-6-phenyl-2H-pyran

Refernces

• 1、 Snegirev, V. F.,Galakhov, M. V.,Petrov, V. A.,Makarov, K. N.,Bakhmutov, V. I.. "POLYFLUORINATED ANIONS AND CATIONS - INTERMEDIATES IN REACTIONS OF FLUORINE-CONTAINING VINYL ETHERS". . p. 1194 - 1200. Retrieved 2007/10/02.