trans-4-Tridecen-1-OL

Base Information

• Chemical Name: trans-4-Tridecen-1-OL
• CAS No.: 75568-02-4
• Molecular Formula: C₁₃H₂₆O
• Molecular Weight: 198.349
• Nikkaji Number: J1.033.652J,J2.374.305A
• Mol file: 75568-02-4.mol

Synonyms:TRANS-4-TRIDECEN-1-OL;75568-02-4;(E)-tridec-4-en-1-ol;SCHEMBL1425506;SCHEMBL1425509;trans-4-Tridecen-1-ol;95%;MFCD00236368

Chemical Property of trans-4-Tridecen-1-OL

Chemical Property:

• Boiling Point: 128°C 9mm
• PSA: 20.23000
• Density: 0,871 g/cm3
• LogP: 4.06570
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 198.198365449
• Heavy Atom Count: 14
• Complexity: 118

Purity/Quality:

98%min ^*data from raw suppliers

TRANS-4-TRIDECEN-1-OL 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC=CCCCO
• Isomeric SMILES: CCCCCCCC/C=C/CCCO

Technology Process of trans-4-Tridecen-1-OL

There total 16 articles about trans-4-Tridecen-1-OL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

n-hexylmagnesium bromide (3761-92-0) + (E)-7-bromohept-4-en-1-ol (139269-67-3) → (4E)-tridec-4-en-1-ol (75568-02-4)

Guidance literature:

dilithium tetrachlorocuprate; In tetrahydrofuran; 1) -60 to 25 deg C, 30 min, 2) 25 deg C, 30 min;

Reference yield: 88.0%

trans-tridec-4-enoic acid ethyl ester (43044-68-4) → (4E)-tridec-4-en-1-ol (75568-02-4)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1134/S1070428013050059

Reference yield:

2-hydroxytetrahydrofuran (5371-52-8) + nonyl alcohol (143-08-8) → (4E)-tridec-4-en-1-ol (75568-02-4)

Guidance literature:

With hydrogen bromide; sodium methylate; triphenylphosphine; In water;

upstream raw materials:

3,4-dihydro-2H-pyran

diethyl ether

octylmagnesium bromide

formaldehyd

Downstream raw materials:

tridec-4E-enyl acetate

Refernces

• 1、 Gruenanger, Christian U.,Breit, Bernhard. "Remote control of regio- and diastereoselectivity in the hydroformylation of bishomoallylic alcohols with catalytic amounts of a reversibly bound directing group". supporting information; experimental part. p. 967 - 970. Retrieved 2010/05/02.
• 2、 Ivanova, N. M.,Cheskis, B. E.,Moiseenkov, A. M.,Nefedov, O. M.. "ALKYLATION OF ACETYLCYCLOPROPANE CYCLOHEXYLIMINE BY ETHYLENE OXIDE DERIVATIVES AS A KEY STEP IN THE SYNTHESIS OF SOME INSECT ACETOGENIN PHEROMONES". . p. 1853 - 1857. Retrieved 2007/10/02.