methylacridinium hexacarbonylvanadate

Base Information

• Chemical Name: methylacridinium hexacarbonylvanadate
• CAS No.: 112713-44-7
• Molecular Formula: C₆O₆V*C₁₄H₁₂N
• Molecular Weight: 413.26
• Mol file: 112713-44-7.mol

Synonyms:methylacridinium hexacarbonylvanadate

Chemical Property of methylacridinium hexacarbonylvanadate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of methylacridinium hexacarbonylvanadate

There total 1 articles about methylacridinium hexacarbonylvanadate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

sodium hexacarbonylvanadate (15602-41-2) + N-methylacridinium iodide (948-43-6) → methylacridinium hexacarbonylvanadate (112713-44-7)

Guidance literature:

In water; Treating (N2 or Ar) of aq. soln. of (Me-Acr)I with Na(V(CO)6); Filtn. of ppt., drying over P4H10 at atm. pressure under exclusion of light, elem. anal.;

DOI:10.1021/om00095a011

Reference yield: 94.0%

methylacridinium hexacarbonylvanadate (112713-44-7) → vanadium hexacarbonyl (14024-00-1) + 10,10'-dimethyl-9,10,9',10'-tetrahydro-[9,9']biacridinyl (3295-69-0)

Guidance literature:

Heating of starting compd. (40°C, 1E-2 Torr) for 3 h, during which green color of solid turns gray.; Spect. (IR) identification of blue-black resulted solid as V(CO)6 and anal. and spect. (IR) identification of org. residue.;

DOI:10.1021/om00095a011

Reference yield:

methylacridinium hexacarbonylvanadate (112713-44-7) → (hexacarbonyl)vanadinate(1-) (20644-87-5) + 10,10'-dimethyl-9,10,9',10'-tetrahydro-[9,9']biacridinyl (3295-69-0)

Guidance literature:

In tetrahydrofuran; byproducts: CO; Treating of starting compd. in the dark with THF, stirring (10 h, room temp.); Evolution of gas (CO by gas chromy.) occurs within the addn.' time. IR spectrum of yellow soln. reveals presence of V(CO)6 anion. Sepn. of colorless org. solid after partial evapn. of solvent, filtn., spect. identification.;

DOI:10.1021/om00095a011

upstream raw materials:

sodium hexacarbonylvanadate

N-methylacridinium iodide

Downstream raw materials:

(hexacarbonyl)vanadinate^(1-)

10,10'-dimethyl-9,10,9',10'-tetrahydro-[9,9']biacridinyl

vanadium hexacarbonyl

Refernces