(S)-(+)-s-butyl phenyl sulfide

Base Information

• Chemical Name: (S)-(+)-s-butyl phenyl sulfide
• CAS No.: 119785-70-5
• Molecular Formula: C₁₀H₁₄S
• Molecular Weight: 166.287
• Mol file: 119785-70-5.mol

Synonyms:(S)-(+)-s-butyl phenyl sulfide

Chemical Property of (S)-(+)-s-butyl phenyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-(+)-s-butyl phenyl sulfide

There total 3 articles about (S)-(+)-s-butyl phenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

(R)-(-)-2-iodobutane (22156-92-9) + sodium thiophenolate (930-69-8) → (S)-(+)-s-butyl phenyl sulfide (119785-70-5)

Guidance literature:

In acetonitrile;

DOI:10.1002/1099-1395(200102)14:2<81::AID-POC338>3.0.CO;2-Z

Reference yield:

(S)-2-bromobutane (78-76-2,5787-31-5,5787-33-7,5787-32-6) + sodium thiophenolate (930-69-8) → (S)-(+)-s-butyl phenyl sulfide (119785-70-5)

Guidance literature:

In ethanol;

DOI:10.1021/jo00283a010

Reference yield:

(R)-(-)-s-butyl bromide (5787-33-7) + thiophenol (108-98-5) → (S)-(+)-s-butyl phenyl sulfide (119785-70-5)

Guidance literature:

DOI:10.1246/bcsj.63.2593

upstream raw materials:

(S)-2-bromobutane

sodium thiophenolate

(R)-(-)-s-butyl bromide

thiophenol

Downstream raw materials:

(R_S,S_C)-(1-methylpropylthio)benzene-S-oxide

(S_S,S_C)-(1-methylpropylthio)benzene-S-oxide

Refernces

• 1、 Umemura, Kazuyuki,Matsuyama, Haruo,Kamigata, Nobumasa. "Alkylation of Several Nucleophiles with Alkylsulfonium Salts". . p. 2593 - 2600. Retrieved 2007/10/02.