1,1,1-Trimethylolethane dinitrate

Base Information

• Chemical Name: 1,1,1-Trimethylolethane dinitrate
• CAS No.: 84051-79-6
• Molecular Formula: C₅H₁₀N₂O₇
• Molecular Weight: 210.144
• Mol file: 84051-79-6.mol

Synonyms:1,1,1-Trimethylolethane dinitrate

Chemical Property of 1,1,1-Trimethylolethane dinitrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1,1-Trimethylolethane dinitrate

There total 2 articles about 1,1,1-Trimethylolethane dinitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.5%

trimethylolethane trinitrate (3032-55-1) → 3-hydroxymethyl-3-methyloxethane (3143-02-0) + 2-(hydroxymethyl)-2-methylpropane-1,3-diol (77-85-0) + 1,1,1-Trimethylolethane mononitrate (84051-80-9) + 1,1,1-Trimethylolethane dinitrate (84051-79-6) + 3-methyl-3-(nitroxymethyl)oxetane (84051-81-0)

Guidance literature:

With sodium hydroxide; In methanol; water; at 55 ℃; for 86.1667h; Product distribution; Rate constant; Thermodynamic data; var. NaOH conc., var. solv., solv. effect, ΔH(excit.), ΔF(excit.), ΔS(excit.);

DOI:10.1021/jo00151a008

Reference yield:

trimethylolethane trinitrate (3032-55-1) → ethyl nitrate (625-58-1) + 1,1,1-Trimethylolethane mononitrate (84051-80-9) + 1,1,1-Trimethylolethane dinitrate (84051-79-6) + 3-methyl-3-(nitroxymethyl)oxetane (84051-81-0)

Guidance literature:

With sodium hydroxide; In ethanol; Heating;

DOI:10.1021/jo00151a008

Reference yield: 24.0%

1,1,1-Trimethylolethane dinitrate (84051-79-6) → 3-hydroxymethyl-3-methyloxethane (3143-02-0) + 2-(hydroxymethyl)-2-methylpropane-1,3-diol (77-85-0) + ethyl nitrate (625-58-1) + 1,1,1-Trimethylolethane mononitrate (84051-80-9) + 3-methyl-3-(nitroxymethyl)oxetane (84051-81-0)

Guidance literature:

With sodium hydroxide; In ethanol; water; at 55 ℃; for 3.10833h; Product distribution; Rate constant; var. NaOH conc.;

DOI:10.1021/jo00151a008

upstream raw materials:

trimethylolethane trinitrate

Downstream raw materials:

3-hydroxymethyl-3-methyloxethane

2-(hydroxymethyl)-2-methylpropane-1,3-diol

ethyl nitrate

1,1,1-Trimethylolethane mononitrate

Refernces