tris(benzyloxymethyl)carbinol

Base Information

• Chemical Name: tris(benzyloxymethyl)carbinol
• CAS No.: 14869-33-1
• Molecular Formula: C₂₅H₂₈O₄
• Molecular Weight: 392.495
• Mol file: 14869-33-1.mol

Synonyms:tris(benzyloxymethyl)carbinol

Chemical Property of tris(benzyloxymethyl)carbinol

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of tris(benzyloxymethyl)carbinol

There total 2 articles about tris(benzyloxymethyl)carbinol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

Benzyloxymethyl chloride (3587-60-8) + Diethyl carbonate (105-58-8,76619-83-5) → tris(benzyloxymethyl)carbinol (14869-33-1)

Guidance literature:

Benzyloxymethyl chloride; With iodine; magnesium; mercury dichloride; In tetrahydrofuran; Heating;

Diethyl carbonate; In tetrahydrofuran; at 22 ℃; for 24h;

DOI:10.1021/ja0524043

Reference yield:

Benzyloxy-methyl-magnesiumchlorid (826-19-7) + Diethyl carbonate (105-58-8,76619-83-5) → tris(benzyloxymethyl)carbinol (14869-33-1)

Guidance literature:

In tetrahydrofuran;

Reference yield:

4-methyleneoxetan-2-one (674-82-8,2130-41-8) + tris(benzyloxymethyl)carbinol (14869-33-1) → 3-oxo-butyric acid 2-benzyloxy-1,1-bis-benzyloxymethyl-ethyl ester

Guidance literature:

With dmap; In diethyl ether; at 22 ℃; for 2.5h;

DOI:10.1021/ja0524043

upstream raw materials:

Benzyloxy-methyl-magnesiumchlorid

Diethyl carbonate

Benzyloxymethyl chloride

Downstream raw materials:

tris(benzyloxymethyl)methyl diazoacetate

Refernces