m-nitrobenzoic anhydride

Base Information

• Chemical Name: m-nitrobenzoic anhydride
• CAS No.: 69859-37-6
• Molecular Formula: C₁₄H₈N₂O₇
• Molecular Weight: 316.227
• Mol file: 69859-37-6.mol

Synonyms:m-nitrobenzoic anhydride

Chemical Property of m-nitrobenzoic anhydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of m-nitrobenzoic anhydride

There total 14 articles about m-nitrobenzoic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3-nitrobenzoic acid (121-92-6) → m-nitrobenzoic anhydride (69859-37-6)

Guidance literature:

With N,N-bis[2-oxo-3-oxazolidinyl]phosphorodiamidic chloride; triethylamine; In acetonitrile; at 20 ℃; for 0.5h;

DOI:10.1055/s-1981-29544

Reference yield: 97.0%

m-nitrobenzoic acid chloride (121-90-4) → m-nitrobenzoic anhydride (69859-37-6)

Guidance literature:

With bis(triphenylphosphine)dichlorocobalt(II); tetrabutylammomium bromide; sodium hydrogencarbonate; In acetonitrile; at 120 ℃; for 12h;

DOI:10.1080/00397919408010249

Reference yield: 92.0%

potassium m-nitrobenzoate (18312-48-6) + 3-nitrobenzoic acid (121-92-6) → m-nitrobenzoic anhydride (69859-37-6)

Guidance literature:

3-nitrobenzoic acid; With trichloroisocyanuric acid; triphenylphosphine; In dichloromethane; at 0 - 20 ℃;

potassium m-nitrobenzoate; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1515/chempap-2015-0042

upstream raw materials:

(3-nitro-benzoic acid )-oxalic acid-anhydride

m-nitrobenzoic acid chloride

3-nitrobenzoic acid

acetic acid-(3-nitro-benzoic acid )-anhydride

Downstream raw materials:

m-nitrobenzoic acid chloride

3-Nitro-N-(3-propionylamino-phenyl)-benzamide

N-(3-Isobutyrylamino-phenyl)-3-nitro-benzamide

3-Nitrobenzyl alcohol

Refernces

• 1、 Kaur, Avneet,Pathak, Dharam P.,Sharma, Vidushi,Wakode, Sharad. "Synthesis, molecular docking, and pharmacological evaluation of N-(2-(3,5-dimethoxyphenyl)benzoxazole-5-yl)benzamide derivatives as selective COX-2 inhibitors and anti-inflammatory agents". . . Retrieved 2018/05/15.
• 2、 Kaur, Avneet,Wakode, Sharad,Pathak, Dharam P.,Sharma, Vidushi,Shakya, Ashok K.. "Synthesis, cyclooxygenase-2 inhibition, anti-inflammatory evaluation and docking study of substituted-n-(3,4,5-trimethoxyphenyl)-benzo[d]oxazole derivatives". . p. 660 - 673. Retrieved 2018/11/06.