Technology Process of 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside
There total 1 articles about 2',4',6'-Trimethoxyphenyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 49 percent / n-BuLi, N,N,N',N'-tetramethylenediamine, sulfur / hexane / 1.) reflux, 2 h, 2.) reflux, 3 h
2: 73 percent / NaH / dimethylformamide / 1.) r.t., 10 min, 2.) 3 h
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine; sodium hydride; sulfur;
In
hexane; N,N-dimethyl-formamide;
- Guidance literature:
-
With
sodium methylate;
In
methanol;
for 3h;
Ambient temperature;
- Guidance literature:
-
In
methanol; acetonitrile;
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
electrochemical synthesis: one compartment, three-electrode, air-tight cell, vitrous carbon anode and Pt catode, 0.2 M LiClO4 as supporting electrolyte, constant potential 1.20 V (vs standard calomel reference electrode);