Technology Process of Methyldiphenylbismuthine, 95
There total 4 articles about Methyldiphenylbismuthine, 95 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
methanol;
In
tetrahydrofuran; diethyl ether; benzene;
byproducts: Bi(C6H5)3; react. under N2 in dry N2-satd. solvents, addn. of 2 M soln. of PhLi inbenzene/ether to a soln. of Bi-compd. in THF, -78°C, addn. of CH3OH; evapn. (vac.), distn. of residue (110°C/0.02 Torr);
- Guidance literature:
-
With
water;
In
water;
elem. anal.;
- Guidance literature:
-
With
Mg;
In
tetrahydrofuran; diethyl ether;
soln. of Bi-compound in THF was added dropwise at room temp. with stirring to soln. of CH3I and Mg in Et2O, stirred overnight at room temp. under Ar; solvent was removed at reduced pressure, extd. with petroleum ether, solvent was removed;
DOI:10.1021/om000749i
