thallium(I) cyanide

Base Information

• Chemical Name: thallium(I) cyanide
• CAS No.: 199537-66-1
• Molecular Formula: CN*Tl
• Molecular Weight: 230.401
• Mol file: 199537-66-1.mol

Synonyms:thallium(I) cyanide

Chemical Property of thallium(I) cyanide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of thallium(I) cyanide

There total 1 articles about thallium(I) cyanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thallium cyanide → thallium(I) cyanide (199537-66-1) + ethanedinitrile (460-19-5,25215-76-3)

Guidance literature:

In neat (no solvent); mild heating either static or dynamic vac.;

DOI:10.1006/jssc.2001.9192

Reference yield: 89.0%

thallium(I) cyanide (199537-66-1) + cis,mer-[bis(diphenylphosphino)methane-P][bis(diphenylphosphino)methane-PP']bromodicarbonylmanganese(I) → cis,mer-[bis(diphenylphosphino)methane-P][bis(diphenylphosphino)methane-PP']dicarbonylcyanomanganese(I)-dichloromethane (1/1)

Guidance literature:

With CH₂Cl₂; In dichloromethane; under Ar, cis,mer-MnBr(CO)2(dppm-PP')(dppm-P) (0.729 mmol) and TlCN (0.868 mmol) stirred with CH2Cl2 for 2 h at room temp.; filtered, evapd. in vac., solid washed with hexane, recrystd. from concd. CH2Cl2 soln. at -10°C; elem. anal.;

DOI:10.1016/0022-328X(87)80157-2

Reference yield:

thallium(I) cyanide (199537-66-1) + iodine (7553-56-2,12190-71-5,8031-47-8) → cyanogen iodide (506-78-5)

Guidance literature:

In water; heating with H2O and I2;; ICN sublimes;;

Downstream raw materials:

cyanogen iodide

thallium(I) sulfide

thallium(I) thiocyanate

Refernces