[(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)]

Base Information

• Chemical Name: [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)]
• CAS No.: 1015065-66-3
• Molecular Formula: C₃₄H₂₆AuFeN₂P
• Molecular Weight: 746.381
• Mol file: 1015065-66-3.mol

Synonyms:[(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)]

Chemical Property of [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)]

There total 1 articles about [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

[AuCl((diphenylphosphanyl)ferrocene-κP)] (933779-29-4) + 5-ethynyl-2,2'-bipyridine (162318-34-5) → [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)] (1015065-66-3)

Guidance literature:

With CuI; In diethylamine; (N2); std. Schlenk technique; CuI was added to soln. of Fe complex and alkyne in Et2NH; soln. was stirred at 25 °C for 16 h; filtered through Celite; volatiles removed (vac.); chromd. (silica gel, Et2O/hexane, 4/1); evapd. (vac.); elem. anal.;

DOI:10.1021/om701021y

Reference yield: 96.0%

[(η(5)-C5H4SiMe3)2Ti(C.tplbond.CSiMe3)2Cu(NCMe)]PF6 + [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)] (1015065-66-3) → [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)Cu(Me3SiCC)2Ti(η5-C5H4SiMe3)2]PF6

Guidance literature:

In tetrahydrofuran; (N2); std. Schlenk technique; Ti complex was added to soln. of Fe-Au complex in THF; stirred at 25°C for 3 h; filtered through Celite; evapd. (vac.); washed (petroleum ether); dried (vac.); elem. anal.;

DOI:10.1021/om701021y

Reference yield: 78.0%

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) + [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)] (1015065-66-3) → [(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)Mo(CO)4] (1034927-46-2)

Guidance literature:

In tetrahydrofuran; dichloromethane; (N2); std. Schlenk technique; Mo complex (1 equiv.) was added to soln. of Fe-Au complex in CH2Cl2/THF (5/1); stirred at 25°C for 15 h; volatiles removed (vac.); washed (Et2O); dried (vac.); elem. anal.;

DOI:10.1021/om701021y

upstream raw materials:

[AuCl((diphenylphosphanyl)ferrocene-κP)]

5-ethynyl-2,2'-bipyridine

Downstream raw materials:

[(η5-C5H5)Fe(η5-C5H4PPh2)Au(CC-2,2'-bipyridyl-5-yl)Mo(CO)4]

Refernces