bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate

Base Information

• Chemical Name: bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate
• CAS No.: 1437306-85-8
• Molecular Formula: C₉₆H₁₇₂O₁₂
• Molecular Weight: 1518.41
• Mol file: 1437306-85-8.mol

Synonyms:bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate

Chemical Property of bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate

There total 3 articles about bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.1%

trioleoylglycerol (122-32-7) → octadec-9-enoic acid propane-1,2,3-triyl ester (6915-08-8,69466-36-0) + 18-bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl)-1,1-3-(octadec-9-enoyloxy)propane-1,2-diyl dioctadec-9-enedioate (1437306-86-9) + 1-(21,43-bis((octadec-9-enoyloxy)methyl)-18,23,40,45,62,68-hexaoxo-19,22,41,44,63,67-hexaoxapentaoctaconta-9,31,53,76-tetraen-65-yl) 18-(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate (1437306-87-0) + 1-(21,42-bis((octadec-9-enoyloxy)methyl)-18,23,40,45,62,68-hexaoxo-19,22,41,44,63,67-hexaoxapentaoctaconta-9,31,53,76-tetraen-65-yl)18-(2-(18-(1,3-bis(octadec-9-enoyloxy)propan-2-yloxy)-18-oxooctadec-9-enoyloxy)-3-(octadec-9-enoyloxy)propyl) octadec-9-enedioate + bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate (1437306-85-8)

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In neat (no solvent); at 38 ℃; for 6h; Overall yield = 21.4 %; Inert atmosphere;

DOI:10.1007/s11746-012-2106-y

Reference yield: 12.8%

trioleoylglycerol (122-32-7) → octadec-9-enoic acid propane-1,2,3-triyl ester (6915-08-8,69466-36-0) + 18-bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl)-1,1-3-(octadec-9-enoyloxy)propane-1,2-diyl dioctadec-9-enedioate (1437306-86-9) + 6,23-dioxo-1,5-dioxacyclotricos-14-en-3-yl octadec-9-enoate + 5,22-dioxo-1,4-dioxacyclodocos-13-en-2-yl-methyl octadec-9-enoate + bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate (1437306-85-8) + 1-(2,3-bis(octadec-9-enoyloxy)propyl) 18-(5,22-dioxo-1,4-dioxacyclodocos-13-en-2-yl)methyl octadec-9-enedioate + 1-(1,3-bis(octadec-9-enoyloxy)propan-2-yl)18-(6,23-dioxo-1,5-dioxacyclotricos-14-en-3-yl) octadec-9-enedioate

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 38 ℃; for 6h; Overall yield = 26.7 %; Inert atmosphere;

DOI:10.1007/s11746-012-2106-y

Reference yield: 8.1%

trioleoylglycerol (122-32-7) → octadec-9-enoic acid propane-1,2,3-triyl ester (6915-08-8,69466-36-0) + 6,23-dioxo-1,5-dioxacyclotricos-14-en-3-yl octadec-9-enoate + 5,22-dioxo-1,4-dioxacyclodocos-13-en-2-yl-methyl octadec-9-enoate + bis(1,3-bis(octadec-9-enoyloxy)propan-2-yl) octadec-9-enedioate (1437306-85-8) + 1-(2,3-bis(octadec-9-enoyloxy)propyl) 18-(5,22-dioxo-1,4-dioxacyclodocos-13-en-2-yl)methyl octadec-9-enedioate + 1-(1,3-bis(octadec-9-enoyloxy)propan-2-yl)18-(6,23-dioxo-1,5-dioxacyclotricos-14-en-3-yl) octadec-9-enedioate + bis (6,23-dioxo-1,5-dioxacyclotricos-14-en-3-yl) octadec-9-enedioate (1437306-89-2) + 18-bis (6,23-dioxo-1,5-dioxacyclotricos-14-en-3-yl)-1,1-2(octadec-9-enoyloxy)propane-1,3-diyl dioctadec-9-enedioate (1437306-90-5)

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 38 ℃; for 6h; Overall yield = 28.3 %; Inert atmosphere;

DOI:10.1007/s11746-012-2106-y

upstream raw materials:

trioleoylglycerol

Refernces