2-Bromotetradecane

Base Information

• Chemical Name: 2-Bromotetradecane
• CAS No.: 74036-95-6
• Molecular Formula: C14H29 Br
• Molecular Weight: 277.288
• Hs Code.: 2903399090
• DSSTox Substance ID: DTXSID80510172
• Nikkaji Number: J750.494B
• Mol file: 74036-95-6.mol

Synonyms:2-BROMOTETRADECANE;74036-95-6;SCHEMBL1003662;DTXSID80510172;WZGQIDWFBFDMLE-UHFFFAOYSA-N;MFCD00045033;AKOS009157417;FT-0611614

Chemical Property of 2-Bromotetradecane

Chemical Property:

• Vapor Pressure: 0.00131mmHg at 25°C
• Refractive Index: 1.4600
• Boiling Point: 160-161°C 8mm
• Flash Point: 160-161°C/8mm
• PSA: 0.00000
• Density: 1.014g/cm³
• LogP: 6.08080
• XLogP3: 7.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 11
• Exact Mass: 276.14526
• Heavy Atom Count: 15
• Complexity: 112

Purity/Quality:

99% ^*data from raw suppliers

2-BROMOTETRADECANE 95.00% ^*data from reagent suppliers

Safty Information:

• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCC(C)Br

Technology Process of 2-Bromotetradecane

There total 2 articles about 2-Bromotetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-tetradecene (1120-36-1) → 1-Bromotetradecane (112-71-0) + 2-bromotetradecane (74036-95-6)

Guidance literature:

With acetic acid; In 1,4-dioxane; 1,2-dichloro-ethane;

DOI:10.1016/j.tetlet.2017.02.020

Reference yield:

C20H34Br2Te (83486-08-2) → diphenyl ditelluride (32294-60-3) + 2-bromotetradecane (74036-95-6)

Guidance literature:

With sodium bromide; In N,N-dimethyl-formamide; at 70 ℃; Yield given;

DOI:10.1246/cl.1982.1081

Reference yield:

2-bromotetradecane (74036-95-6) → tetradecane (629-59-4)

Guidance literature:

With tributyl-amine; cyclohexa-1,4-diene; 4-(3,6-dimethoxycarbazol-9-yl)-3-(trifluoromethyl)benzoic acid; In tetrahydrofuran; at 26 ℃; for 42h; Inert atmosphere; Schlenk technique; Irradiation;

DOI:10.1002/asia.201600538

upstream raw materials:

C₂₀H₃₄Br₂Te

1-tetradecene

Downstream raw materials:

tetradecan-1-yl phenyl telluride

1-tetradecene

tetradecan-2-ol

tetradecan-2-one

Refernces

• 1、 Chikamatsu, Kiyofumi,Otsubo, Tetsuo,Ogura, Fumio,Yamaguchi, Hachiro. "PREPARATION OF ALKYL HALIDES VIA ORGANOTELLURIUMS". . p. 1081 - 1084. Retrieved 2007/10/02.