5-bromo-2-phenylbenzo[d]thiazole

Base Information

• Chemical Name: 5-bromo-2-phenylbenzo[d]thiazole
• CAS No.: 305372-56-9
• Molecular Formula: C₁₃H₈BrNS
• Molecular Weight: 290.183
• Mol file: 305372-56-9.mol

Synonyms:5-bromo-2-phenylbenzo[d]thiazole

Chemical Property of 5-bromo-2-phenylbenzo[d]thiazole

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-bromo-2-phenylbenzo[d]thiazole

There total 16 articles about 5-bromo-2-phenylbenzo[d]thiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

N-(3-bromophenyl)benzothioamide (108752-45-0) → 5-bromo-2-phenylbenzo[d]thiazole (305372-56-9)

Guidance literature:

With rubidium carbonate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; oxygen; tris-(o-tolyl)phosphine; In water; at 40 ℃; for 24h; under 760.051 Torr;

DOI:10.1055/s-0031-1291164

Reference yield: 84.0%

N-(3-bromophenyl)benzothioamide (108752-45-0) → 5-bromo-2-phenylbenzo[d]thiazole (305372-56-9) + 7-bromo-2-phenylbenzo[d]thiazole (36247-07-1)

Guidance literature:

With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; oxygen; 1,8-diazabicyclo[5.4.0]undec-7-ene; In N,N-dimethyl-formamide; at 20 ℃; for 24h; Irradiation;

DOI:10.1021/ol2028866

Reference yield: 80.0%

5-bromo-benzthiazole (768-11-6) + diphenyliodonium tetrafluoroborate → 5-bromo-2-phenylbenzo[d]thiazole (305372-56-9)

Guidance literature:

With potassium phosphate; palladium diacetate; tricyclohexylphosphine; In 5,5-dimethyl-1,3-cyclohexadiene; at 85 ℃; for 28h; Green chemistry;

upstream raw materials:

N-(3-bromophenyl)benzothioamide

N-(3-bromophenyl)benzamide

4-bromo-1-chloro-2-nitrobenzene

benzylamine

Refernces

• 1、 Xu, Ze-Ming,Li, Hong-Xi,Young, David James,Zhu, Da-Liang,Li, Hai-Yan,Lang, Jian-Ping. "Exogenous Photosensitizer-, Metal-, and Base-Free Visible-Light-Promoted C-H Thiolation via Reverse Hydrogen Atom Transfer". supporting information. p. 237 - 241. Retrieved 2019/01/10.
• 2、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF". Paragraph 0094-0112; 0115-0122. . Retrieved 2019/06/26.