Dichloro[pentafluoro(phenyl)-lambda~7~-chloranyl]propylsilane

Base Information

• Chemical Name: Dichloro[pentafluoro(phenyl)-lambda~7~-chloranyl]propylsilane
• CAS No.: 78900-02-4
• Molecular Formula: C₉H₆Cl₃F₅Si
• Molecular Weight: 343.583
• DSSTox Substance ID: DTXSID50700543
• Wikidata: Q82631935
• Mol file: 78900-02-4.mol

Synonyms:DTXSID50700543;Dichloro[pentafluoro(phenyl)-lambda~7~-chloranyl]propylsilane

Chemical Property of Dichloro[pentafluoro(phenyl)-lambda~7~-chloranyl]propylsilane

Chemical Property:

• Vapor Pressure: 0.0727mmHg at 25°C
• Melting Point: 27-30°C
• Refractive Index: 1.462
• Boiling Point: 99°C 0,75mm
• Flash Point: 96.8°C
• PSA: 0.00000
• Density: 1.495
• LogP: 5.16570
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 347.969401
• Heavy Atom Count: 18
• Complexity: 349

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trichloro[3-(pentafluorophenyl)propyl]silane >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[Si](Cl)(Cl)Cl(C1=CC=CC=C1)(F)(F)(F)(F)F

Technology Process of Dichloro[pentafluoro(phenyl)-lambda~7~-chloranyl]propylsilane

There total 2 articles about Dichloro[pentafluoro(phenyl)-lambda~7~-chloranyl]propylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.5%

1-allyl-2,3,4,5,6-pentafluorobenzene (1736-60-3) → 1-(pentafluorphenyl)-3-trichlorsilylpropan (78900-02-4)

Guidance literature:

With trichlorosilane; platinum on activated charcoal; at 100 ℃; for 2h;

DOI:10.1016/S0022-1139(00)82259-9

Reference yield:

bromopentafluorobenzene (344-04-7) → 1-(pentafluorphenyl)-3-trichlorsilylpropan (78900-02-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) Mg / 1.) ether, 2.) ether

2: 89.5 percent / HSiCl₃ / Pt/C / 2 h / 100 °C

With trichlorosilane; magnesium; platinum on activated charcoal;

DOI:10.1016/S0022-1139(00)82259-9

upstream raw materials:

1-allyl-2,3,4,5,6-pentafluorobenzene

bromopentafluorobenzene

Refernces