toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester

Base Information

• Chemical Name: toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester
• CAS No.: 132004-78-5
• Molecular Formula: C₃₁H₅₆O₃S
• Molecular Weight: 508.85
• Mol file: 132004-78-5.mol

Synonyms:toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester

Chemical Property of toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester

There total 1 articles about toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-decylteradecanol (58670-89-6) + p-toluenesulfonyl chloride (98-59-9) → toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester (132004-78-5)

Guidance literature:

2-decylteradecanol; With trimethylamine hydrochloride; triethylamine; In dichloromethane; for 0.333333h; Cooling with ice;

p-toluenesulfonyl chloride; In dichloromethane; at 0 ℃; for 3h;

DOI:10.1039/c5cc03789a

Reference yield: 70.0%

toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester (132004-78-5) + 2,4-Dihydroxybenzaldehyde (95-01-2) → 2,4-bis-(2-decyltetradecyloxy)phenylmethanol

Guidance literature:

toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester; 2,4-Dihydroxybenzaldehyde; potassium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 16h;

With sodium tetrahydroborate; In tetrahydrofuran; methanol; at 0 ℃; for 1h;

With acetic acid; In tetrahydrofuran; methanol;

Reference yield: 70.0%

toluene-4-sulfonic acid 2-decyl-1-tetradecyl ester (132004-78-5) + 3,3',4,4'-tetrahydroxybenzil (6309-15-5) → 3,3',4,4'-tetra(2-decyltetradecyloxy)benzil (1332655-16-9)

Guidance literature:

With potassium carbonate; In N,N-dimethyl acetamide; at 70 ℃; for 48h;

DOI:10.1039/c1cc12640g

upstream raw materials:

2-decylteradecanol

p-toluenesulfonyl chloride

Downstream raw materials:

3,3',4,4'-tetra(2-decyltetradecyloxy)benzil

2-decyl-1-tetradecylamine

Refernces

• 1、 Lee, Ji Eun,Kim, Yebyeol,Ha, Jong-Jin,An, Tae Kyu,Kim, Yun-Hi. "Synthesis of thienopyrrolodione-based copolymers and their application in organic thin-film transistors". . p. 5662 - 5668. Retrieved 2017/05/08.
• 2、 Wang,Sun,Günba,Zhang,Grozema,Xiao,Jin. "A bundled-stack discotic columnar liquid crystalline phase with inter-stack electronic coupling". supporting information. p. 11837 - 11840. Retrieved 2015/07/15.