phenyl selenobenzoate

Base Information

• Chemical Name: phenyl selenobenzoate
• CAS No.: 38447-68-6
• Molecular Formula: C₁₃H₁₀OSe
• Molecular Weight: 261.182
• Mol file: 38447-68-6.mol

Synonyms:phenyl selenobenzoate

Chemical Property of phenyl selenobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl selenobenzoate

There total 45 articles about phenyl selenobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

diphenyl diselenide (1666-13-3) + benzoyl chloride (98-88-4) → phenyl selenobenzoate (38447-68-6)

Guidance literature:

With indium; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; at 50 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.08.076

Reference yield: 95.0%

phenyl trimethylsilyl selenide (33861-17-5) + benzoyl chloride (98-88-4) → phenyl selenobenzoate (38447-68-6)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1055/s-0030-1261195

Reference yield: 95.0%

trimethylstannyl phenyl selenide (4848-71-9) + benzoyl chloride (98-88-4) → phenyl selenobenzoate (38447-68-6)

Guidance literature:

With {2,6-bis[(phenylseleno)methyl]phenyl}palladium chloride; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1021/jo051266x

upstream raw materials:

Benzoyl bromide

Thallous Phenyl Selenide

carbon monoxide

diphenyl diselenide

Downstream raw materials:

benzoic acid methyl ester

(Z)-1-benzoyl-2-(phenylseleno)-1-octene

diphenyl diselenide

N-(4-methoxybenzyl)benzamide

Refernces

• 1、 Cheng, Ying,Jin, Weiwei,Liu, Jing,Lu, Liang-Qiu,Luo, Yixin,Qi, Xiaotian,Sun, Peng-Chao,Xiao, Wen-Jing,Zhao, Wei. "Photoredox-Enabled Chromium-Catalyzed Alkene Diacylations". . p. 1879 - 1885. Retrieved 2022/02/07.
• 2、 Dall'Oglio, Evandro L.,Stein, André L.,Vasconcelos, Leonardo G.,Vieira, Lucas C. C.,de Oliveira, Angélica J.,de Oliveira, Sandynara A.. "Synthesis of selenol esters via the reaction of acyl chlorides with diselenides in the presence of Zn dust catalyzed by CoCl2·6H2O". supporting information. . Retrieved 2021/08/25.