4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole

Base Information

• Chemical Name: 4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole
• CAS No.: 83027-21-8
• Molecular Formula: C₂₆H₂₀N₂
• Molecular Weight: 360.458
• Mol file: 83027-21-8.mol

Synonyms:4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole

Chemical Property of 4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole

There total 17 articles about 4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

6,12-diphenyl-dibenzo<1,5>diazocine (7139-42-6) → 4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole (83027-21-8)

Guidance literature:

6,12-diphenyl-dibenzo<1,5>diazocine; With sodium; In tetrahydrofuran; at 20 ℃; for 48h; Inert atmosphere;

With water; In tetrahydrofuran;

DOI:10.1002/ejoc.201200278

Reference yield: 45.0%

6,12-diphenyl-dibenzo[b,f][1,5]diazocine (7139-42-6) + benzyllithium (766-04-1) → 6-exo-benzyl-6,12-diphenyl-5,6-dihydrodibenzo[b,f][1,5]diazocine (1391621-50-3) + 4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole (83027-21-8) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7)

Guidance literature:

6,12-diphenyl-dibenzo[b,f][1,5]diazocine; benzyllithium; With N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane; toluene; at -78 - 25 ℃; for 14h; Inert atmosphere;

With water; In tetrahydrofuran; hexane; toluene; at 25 ℃; Inert atmosphere;

DOI:10.1002/ejoc.201301181

Reference yield:

6,12-diphenyl-dibenzo<1,5>diazocine (7139-42-6) + benzylmagnesium chloride (6921-34-2) → 4b,5,9b,10-tetrahydro-4b,9b-diphenylindolo<3,2-b>indole (83027-21-8) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7)

Guidance literature:

6,12-diphenyl-dibenzo<1,5>diazocine; benzylmagnesium chloride; In tetrahydrofuran; at 20 ℃; for 48h; Reflux; Inert atmosphere;

With water; In tetrahydrofuran;

DOI:10.1002/ejoc.201200278

upstream raw materials:

6,12-diphenyl-dibenzo<1,5>diazocine

tetrahydrofuran

diphenylmethyllithium

Diphenylmethane

Refernces

• 1、 Eisch, John J.,Yu, Kun,Rheingold, Arnold L.. "6,12-Diphenyldibenzo[b,f][1,5]diazocine as an electron-capture agent: Efficient mechanistic probe for SET processes and reagent for the oxidative dimerization of benzylic organometallics". experimental part. p. 3165 - 3171. Retrieved 2012/06/30.