O-(2-bromophenyl)-O,O-diethylthiophosphate

Base Information

• Chemical Name: O-(2-bromophenyl)-O,O-diethylthiophosphate
• CAS No.: 1087408-67-0
• Molecular Formula: C₁₀H₁₄BrO₃PS
• Molecular Weight: 325.163
• Mol file: 1087408-67-0.mol

Synonyms:O-(2-bromophenyl)-O,O-diethylthiophosphate

Chemical Property of O-(2-bromophenyl)-O,O-diethylthiophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-(2-bromophenyl)-O,O-diethylthiophosphate

There total 2 articles about O-(2-bromophenyl)-O,O-diethylthiophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-hydroxybromobenzene (95-56-7) + diethyl phosphorochloridothioate (2524-04-1) → O-(2-bromophenyl)-O,O-diethylthiophosphate (1087408-67-0)

Guidance literature:

With dmap; triethylamine; In tetrahydrofuran;

DOI:10.1055/s-0028-1087362

Reference yield:

diethyl phosphorochloridothioate (2524-04-1) → O-(2-bromophenyl)-O,O-diethylthiophosphate (1087408-67-0)

Guidance literature:

With pyridine; chlorobenzene; at 130 ℃;

Reference yield: 95.0%

O-(2-bromophenyl)-O,O-diethylthiophosphate (1087408-67-0) → C10H15O3PS (1138036-46-0)

Guidance literature:

O-(2-bromophenyl)-O,O-diethylthiophosphate; With n-butyllithium; In tetrahydrofuran; hexane; at -80 ℃;

With water; ammonium chloride; In tetrahydrofuran; hexane;

DOI:10.1055/s-0028-1087362

upstream raw materials:

diethyl phosphorochloridothioate

2-hydroxybromobenzene

Downstream raw materials:

C₁₀H₁₅O₃PS

C₁₀H₁₅O₄PS

Refernces

• 1、 Dieng, Thierno,Fraix, Aurore,Salaün, Jean-Yves,Dez, Isabelle,Klein Gebbink, Robertus J. M.,Van Koten, Gerard,Jaffrès, Paul-Alain. "Synthesis of O,O-diethyl arylthiophosphonate from O-aryl-O,O- diethylthiophosphate". experimental part. p. 3121 - 3124. Retrieved 2009/06/17.