1-cyclohexyl-2-phenyldisulfane

Base Information

• Chemical Name: 1-cyclohexyl-2-phenyldisulfane
• CAS No.: 29627-27-8
• Molecular Formula: C₁₂H₁₆S₂
• Molecular Weight: 224.391
• Mol file: 29627-27-8.mol

Synonyms:1-cyclohexyl-2-phenyldisulfane

Chemical Property of 1-cyclohexyl-2-phenyldisulfane

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 1-cyclohexyl-2-phenyldisulfane

There total 6 articles about 1-cyclohexyl-2-phenyldisulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

N-(cyclohexyldisulfide)phthalimide (30912-76-6) + phenylboronic acid (98-80-6) → 1-cyclohexyl-2-phenyldisulfane (29627-27-8)

Guidance literature:

With [2,2]bipyridinyl; potassium phosphate; copper diacetate; In tetrahydrofuran; water; at 40 ℃; for 10h; Inert atmosphere;

DOI:10.1021/acscatal.9b04326

Reference yield: 15.0%

Cyclohexanethiol (1569-69-3) + thiophenol (108-98-5) → 1,2-dicyclohexyl disulfide (2550-40-5) + 1-cyclohexyl-2-phenyldisulfane (29627-27-8) + diphenyldisulfane (882-33-7)

Guidance literature:

With 4,6-di-tert-butyl-N-(tert-butyl)-o-aminophenol; In acetonitrile; at 20 ℃; for 4h; Electrochemical reaction;

DOI:10.1149/1945-7111/abfe43

Reference yield:

Cyclohexanethiol (1569-69-3) + thiophenol (108-98-5) → 1-cyclohexyl-2-phenyldisulfane (29627-27-8)

Guidance literature:

With 3,5-di-tert-butyl-1,2-benzoquinone; In 1-methyl-pyrrolidin-2-one; at 20 ℃;

DOI:10.1007/s11172-020-2860-1

upstream raw materials:

N-(cyclohexyldisulfide)phthalimide

phenylboronic acid

dibutyl disulfide

didodecyl disulfide

Refernces

• 1、 Hilt, Gerhard,Otten, Chris Josef,Sattler, Lars Erik. "Alternating Current Electrolysis for the Electrocatalytic Synthesis of Mixed Disulfide via Sulfur–Sulfur Bond Metathesis towards Dynamic Disulfide Libraries". supporting information. . Retrieved 2020/02/27.
• 2、 Zou, Jiaoxia,Chen, Jinhong,Shi, Tao,Hou, Yongsheng,Cao, Fei,Wang, Yongqiang,Wang, Xiaodong,Jia, Zhong,Zhao, Quanyi,Wang, Zhen. "Phthalimide-Carried Disulfur Transfer to Synthesize Unsymmetrical Disulfanes via Copper Catalysis". . p. 11426 - 11430. Retrieved 2019/11/21.