METHYL MYRISTELAIDATE

Base Information

• Chemical Name: METHYL MYRISTELAIDATE
• CAS No.: 72025-18-4
• Molecular Formula: C15H28 O2
• Molecular Weight: 240.386
• Mol file: 72025-18-4.mol

Synonyms:9-Tetradecenoicacid, methyl ester, (E)-

Chemical Property of METHYL MYRISTELAIDATE

Chemical Property:

• Vapor Pressure: 0.000763mmHg at 25°C
• Refractive Index: 1.449
• Boiling Point: 306.6°C at 760 mmHg
• Flash Point: 90.9°C
• PSA: 26.30000
• Density: 0.879g/cm³
• LogP: 4.63650
• Storage Temp.: −20°C

Purity/Quality:

98%Min ^*data from raw suppliers

Methyl myristelaidate analytical standard ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL MYRISTELAIDATE

There total 2 articles about METHYL MYRISTELAIDATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Methyl oleate (112-62-9) + (Z)-7-dodecenyl acetate (14959-86-5) → 5-decene (19689-19-1) + myristelaidic acid methyl ester (72025-18-4) + (E)-7-dodecenyl acetate (16695-41-3) + 1-tetradecene (4084-07-5)

Guidance literature:

In dichloromethane; for 36h; Further byproducts given;

DOI:10.1002/(SICI)1522-2675(19980909)81:9<1616::AID-HLCA1616>3.0.CO;2-P

Reference yield:

1-hexene (592-41-6,25067-06-5) + octadec-9-enoic acid methyl ester (112-62-9) → 1-Decene (872-05-9,17438-89-0,25189-70-2) + methyl 9-decenoate (25601-41-6) + myristelaidic acid methyl ester (72025-18-4) + 1-tetradecene (4084-07-5)

Guidance literature:

With tetramethylstannane; tungsten(VI) chloride; at 20 - 100 ℃; Kinetics; Product distribution; Mechanism;

Reference yield:

myristelaidic acid methyl ester (72025-18-4) → (E)-tetradec-9-en-1-yl acetate (23192-82-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 84.9 percent / LiAlH₄ / diethyl ether

2: 86.6 percent / pyridine / benzene

With pyridine; lithium aluminium tetrahydride; In diethyl ether; benzene;

upstream raw materials:

1-hexene

octadec-9-enoic acid methyl ester

Methyl oleate

(Z)-7-dodecenyl acetate

Downstream raw materials:

9-tetradecyn-1-yl acetate

(E)-tetradec-9-en-1-yl acetate

Refernces

• 1、 Matyska, Bohumir,Dosedlova, Alena,Petrusova, Lidmila,Balcar, Hynek. "COMETATHESIS OF METHYL OLEATE WITH α-OLEFINS". . p. 455 - 461. Retrieved 2007/10/02.