Octanoic acid, 6,6-dimethoxy-, methyl ester

Base Information

• Chemical Name: Octanoic acid, 6,6-dimethoxy-, methyl ester
• CAS No.: 65157-89-3
• Molecular Formula: C11H22 O4
• Molecular Weight: 218.293
• Hs Code.: 2918990090
• Mol file: 65157-89-3.mol

Synonyms:Suberaldehydicacid, methyl ester, dimethyl acetal (7CI); Methyl 8,8-dimethoxyoctanoate

Chemical Property of Octanoic acid, 6,6-dimethoxy-, methyl ester

Chemical Property:

• PSA: 44.76000
• LogP: 2.11890

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Octanoic acid, 6,6-dimethoxy-, methyl ester

There total 4 articles about Octanoic acid, 6,6-dimethoxy-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

methanol (67-56-1) + 2-iodo-cyclooctanone (63641-49-6) → methyl 8-oxooctanoate (3884-92-2) + 8,8-dimethoxyoctanoic acid methyl ester (65157-89-3)

Guidance literature:

With water; at 20 ℃; for 18h; Photolysis;

DOI:10.1246/bcsj.73.1645

Reference yield: 50.0%

1,2-cyclooctene (931-88-4,22770-27-0,3958-30-3,25267-51-0) → 8,8-dimethoxyoctanoic acid methyl ester (65157-89-3) + dimethyl subarate (1732-09-8)

Guidance literature:

1,2-cyclooctene; With water; oxygen; ozone; In methanol; at 0 ℃;

With semicarbazide hydrochloride; In methanol; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1134/S1070428013100023

Reference yield: 30.0%

1,2-cyclooctene (931-88-4,22770-27-0,3958-30-3,25267-51-0) → 8,8-dimethoxyoctanoic acid methyl ester (65157-89-3) + dimethyl subarate (1732-09-8) + methyl 8-hydroxyiminooctanoate

Guidance literature:

1,2-cyclooctene; With water; oxygen; ozone; In methanol; at 0 ℃;

With hydroxylamine hydrochloride; In methanol; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1134/S1070428013100023

upstream raw materials:

methanol

2-iodo-cyclooctanone

1,2-cyclooctene

Downstream raw materials:

(E)-10-hydroxy-dec-2-enoic acid

methyl 8-oxooctanoate

Refernces

• 1、 Ishmuratov,Legostaeva,Garifullina,Botsman,Muslukhov,Tolstikov. "Transformations of peroxide olefin ozonolysis products in methanol in the presence of water". . p. 1415 - 1419. Retrieved 2014/01/06.