C₁₂H₆N₂(C₆H₄OCH₂)2(CH₂OCH₂)3

Base Information

• Chemical Name: C₁₂H₆N₂(C₆H₄OCH₂)2(CH₂OCH₂)3
• CAS No.: 89333-98-2
• Molecular Formula: C₃₂H₃₀N₂O₅
• Molecular Weight: 522.601
• Mol file: 89333-98-2.mol

Synonyms:C₁₂H₆N₂(C₆H₄OCH₂)2(CH₂OCH₂)3

Chemical Property of C₁₂H₆N₂(C₆H₄OCH₂)2(CH₂OCH₂)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₁₂H₆N₂(C₆H₄OCH₂)2(CH₂OCH₂)3

There total 1 articles about C₁₂H₆N₂(C₆H₄OCH₂)2(CH₂OCH₂)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,9-bis-(4-methoxy-phenyl)-1,10-phenanthroline (89333-97-1) → C12H6N2(C6H4OCH2)2(CH2OCH2)3 (89333-98-2)

Guidance literature:

Multi-step reaction with 2 steps

1: chlorure de pyridinium / 200 °C

2: 50 percent / Cs₂CO₃ / dimethylformamide / 65 °C

With pyridine hydrochloride; caesium carbonate; In N,N-dimethyl-formamide;

DOI:10.1016/S0040-4039(00)94049-8

Reference yield: 83.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 2,9-bis(4-(prop-2-yn-1-yloxy)-phenyl)-1,10-phenanthroline (109748-88-1) + C12H6N2(C6H4OCH2)2(CH2OCH2)3 (89333-98-2) → HCCCH2OC6H4C12N2H6C6H4OCH2CCHCuC32N2O5H30(1+)*BF4(1-)=HCCCH2OC6H4C12N2H6C6H4OCH2CCHCuC32N2O5H30BF4 (129447-66-1)

Guidance literature:

In dichloromethane; acetonitrile; Ar-atmosphere; Cu-complex in CH3CN added at room temp. to a stirred soln. of the macrocycle in CH2Cl2; stirred for 0.5 h; diyne phenanthroline in CH2Cl2 added; stirred for 1 h;; evapd.; filtration over silica gel (CH2Cl2; CH2Cl2/1%MeOH);;

Reference yield:

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 2,9-bis-(4-methoxy-phenyl)-1,10-phenanthroline (89333-97-1) + C12H6N2(C6H4OCH2)2(CH2OCH2)3 (89333-98-2) → Cu[CH3OC6H4C5H2NCHCHC5H2NC6H4OCH3][C5H2NCHCHC5H2NC6H4(OCH2CH2)4OC6H4](1+) (95740-42-4)

Guidance literature:

In dichloromethane; acetonitrile; to stirred soln. of (CHC5H2NC6H4(OCH2CH2)2CH2)2O in CH2Cl2 was added soln. of Cu complex under Ar at room temp., after 0.5 h at room temp. was added soln. of (CH3OC6H4C5H2NCH)2 in CH2Cl2, stirred for 1 h at room temp.; evapd.;

DOI:10.1021/ja00297a028

upstream raw materials:

2,9-bis-(4-methoxy-phenyl)-1,10-phenanthroline

Downstream raw materials:

HCCCH₂OC₆H₄C₁₂N₂H₆C₆H₄OCH₂CCHCuC₃₂N₂O₅H₃₀⁽¹⁺⁾*BF₄^(1-)=HCCCH₂OC₆H₄C₁₂N₂H₆C₆H₄OCH₂CCHCuC₃₂N₂O₅H₃₀BF₄

Cu[CH₃OC₆H₄C₅H₂NCHCHC₅H₂NC₆H₄OCH₃][C₅H₂NCHCHC₅H₂NC₆H₄(OCH₂CH₂)4OC₆H₄]⁽¹⁺⁾

Refernces