allyl 2-methylbenzoate

Base Information

• Chemical Name: allyl 2-methylbenzoate
• CAS No.: 3609-56-1
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.215
• Mol file: 3609-56-1.mol

Synonyms:allyl 2-methylbenzoate

Chemical Property of allyl 2-methylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of allyl 2-methylbenzoate

There total 5 articles about allyl 2-methylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

ortho-methylbenzoic acid (118-90-1) + allyl alcohol (107-18-6) → allyl 2-methylbenzoate (3609-56-1)

Guidance literature:

With sulfuric acid; Inert atmosphere; Reflux;

DOI:10.1021/ol301563g

Reference yield: 76.0%

ortho-methylbenzoic acid (118-90-1) + 1-Phenyl-3-buten-1-ol (80735-94-0,936-58-3) → allyl 2-methylbenzoate (3609-56-1)

Guidance literature:

With palladium diacetate; silver carbonate; In 1,2-dichloro-benzene; at 100 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ol501887a

Reference yield:

allyl bromide (106-95-6) → allyl 2-methylbenzoate (3609-56-1)

Guidance literature:

at 160 ℃;

DOI:10.1021/ja01857a054

upstream raw materials:

allyl bromide

ortho-methylbenzoic acid

allyl alcohol

1-Phenyl-3-buten-1-ol

Downstream raw materials:

(Z)-prop-1-enyl 2-methylbenzoate

(E)-prop-1-enyl 2-methylbenzoate

ortho-methylbenzoic acid

2-allyl-6-methylbenzoic acid

Refernces

• 1、 Wang, Yong,Kang, Qiang. "Palladium-catalyzed allylic esterification via C-C bond cleavage of a secondary homoallyl alcohol". supporting information. p. 4190 - 4193. Retrieved 2014/10/15.