METHYL 7-BROMOHEPTANOATE

Base Information

• Chemical Name: METHYL 7-BROMOHEPTANOATE
• CAS No.: 54049-24-0
• Molecular Formula: C8H15BrO2
• Molecular Weight: 223.11
• Hs Code.: 2915900090
• Mol file: 54049-24-0.mol

Synonyms:7-Bromoheptanoicacid methyl ester;Methyl 7-bromoheptanoate;Methyl w-bromoheptanoate;heptanoic acid, 7-bromo-, methyl ester;methyl 7-bromoheptanoate;

Chemical Property of METHYL 7-BROMOHEPTANOATE

Chemical Property:

• Vapor Pressure: 0.0703mmHg at 25°C
• Refractive Index: 1.46
• Boiling Point: 229.2 °C at 760 mmHg
• Flash Point: 118.2 °C
• PSA: 26.30000
• Density: 1.258 g/cm³
• LogP: 2.50480
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Methyl7-Bromoheptanoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of METHYL 7-BROMOHEPTANOATE

There total 10 articles about METHYL 7-BROMOHEPTANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

methanol (67-56-1) + 7-bromoheptanoic acid (30515-28-7) → methyl 7-bromoheptanoate (54049-24-0)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In diethyl ether; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/acs.jnatprod.5b00713

Reference yield: 91.0%

7-bromoheptanoic acid (30515-28-7) + sodium methylate (124-41-4) → methyl 7-bromoheptanoate (54049-24-0)

Guidance literature:

In diethyl ether; at 20 ℃; for 12h;

Reference yield: 83.0%

→ methyl 7-bromoheptanoate (54049-24-0)

Guidance literature:

With bromine; dibromoisocyanuric acid; In dichloromethane; at 20 ℃; for 4h; UV-irradiation;

upstream raw materials:

diazomethane

7-bromoheptanoic acid

1,3,5-cyclohexanetriol

methanol

Downstream raw materials:

7-bromoheptyl alcohol

7-(2-Nitro-phenylselanyl)-heptanoic acid methyl ester

methyl 7-[5-(3-phenoxybenzyl)-1,1-dioxido-1,2,5-thiadiazolidin-2-yl]heptanoate

1-bromo-7-methyl-octane

Refernces

• 1、 Wang, Fang,Becker, Sabine,Minier, Mikael A.,Loas, Andrei,Jackson, Megan N.,Lippard, Stephen J.. "Tuning the Diiron Core Geometry in Carboxylate-Bridged Macrocyclic Model Complexes Affects Their Redox Properties and Supports Oxidation Chemistry". supporting information. p. 11050 - 11058. Retrieved 2017/09/26.
• 2、 -. "A marine natural product (R) - 24-methyl-twenty-five carbon -2, 4, 16- three alkyne -1,6-diol and its antimer synthesis method". . . Retrieved 2019/02/04.