cyanoacrylate benzyl ester-anthracene adduct

Base Information

• Chemical Name: cyanoacrylate benzyl ester-anthracene adduct
• CAS No.: 119858-92-3
• Molecular Formula: C₂₅H₁₉NO₂
• Molecular Weight: 365.431
• Mol file: 119858-92-3.mol

Synonyms:cyanoacrylate benzyl ester-anthracene adduct

Chemical Property of cyanoacrylate benzyl ester-anthracene adduct

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyanoacrylate benzyl ester-anthracene adduct

There total 3 articles about cyanoacrylate benzyl ester-anthracene adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

9,10-dihydro-9,10-endoethanoanthracene-11-cyano-11-carboxylic acid (60722-02-3) + benzyl alcohol (100-51-6,185532-71-2) → cyanoacrylate benzyl ester-anthracene adduct (119858-92-3)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 ℃; for 6h; Inert atmosphere;

DOI:10.1021/ma400837h

Reference yield:

anthracene (120-12-7) → cyanoacrylate benzyl ester-anthracene adduct (119858-92-3)

Guidance literature:

Multi-step reaction with 3 steps

1: boric acid; benzene-1,2-diol / toluene / 18 h / Inert atmosphere; Reflux

2: lithium hydroxide / tetrahydrofuran; water / 25 °C

3: dmap; dicyclohexyl-carbodiimide / dichloromethane / 6 h / 0 °C / Inert atmosphere

With dmap; boric acid; benzene-1,2-diol; dicyclohexyl-carbodiimide; lithium hydroxide; In tetrahydrofuran; dichloromethane; water; toluene;

DOI:10.1021/ma400837h

Reference yield:

ethyl 9,10-dihydro-9,10-endoethanoanthracene-11-cyano-11-carboxylate (19277-46-4) → cyanoacrylate benzyl ester-anthracene adduct (119858-92-3)

Guidance literature:

Multi-step reaction with 2 steps

1: lithium hydroxide / tetrahydrofuran; water / 25 °C

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 6 h / 0 °C / Inert atmosphere

With dmap; dicyclohexyl-carbodiimide; lithium hydroxide; In tetrahydrofuran; dichloromethane; water;

DOI:10.1021/ma400837h

upstream raw materials:

9,10-dihydro-9,10-endoethanoanthracene-11-cyano-11-carboxylic acid

benzyl alcohol

anthracene

ethyl 9,10-dihydro-9,10-endoethanoanthracene-11-cyano-11-carboxylate

Downstream raw materials:

cyanoacrylate benzyl ester

dibenzobarallene

Refernces