METHYL (METHYL 1-THIO-2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANOSID)-URONATE

Base Information

• Chemical Name: METHYL (METHYL 1-THIO-2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANOSID)-URONATE
• CAS No.: 29587-10-8
• Molecular Formula: C₁₄H₂₀O₉S
• Molecular Weight: 364.373
• Mol file: 29587-10-8.mol

Synonyms:Glucopyranosiduronicacid, methyl 1-thio-, methyl ester, triacetate, b-D- (6CI,7CI,8CI)

Chemical Property of METHYL (METHYL 1-THIO-2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANOSID)-URONATE

Chemical Property:

• Melting Point: 118-119 °C
• Boiling Point: 418.0±45.0 °C(Predicted)
• PSA: 139.73000
• Density: 1.31±0.1 g/cm3(Predicted)
• LogP: 0.04240

Purity/Quality:

98% ^*data from raw suppliers

METHYL-(METHYL-1-THIO-2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANOSID)-URONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL (METHYL 1-THIO-2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANOSID)-URONATE

There total 2 articles about METHYL (METHYL 1-THIO-2,3,4-TRI-O-ACETYL-BETA-D-GLUCOPYRANOSID)-URONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methylthiol (74-93-1) + 1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester (21085-72-3) → 2,3,4-Tri-O-acetyl-1-mercaptomethyl-β-D-glucopyranuronsaeure-methylester (29587-10-8)

Guidance literature:

With methanol; potassium ethoxide; at -78 ℃; Behandeln des Reaktionsprodukts mit Acetanhydrid und Pyridin;

Reference yield:

→ 2,3,4-Tri-O-acetyl-1-mercaptomethyl-β-D-glucopyranuronsaeure-methylester (29587-10-8)

Guidance literature:

1-Thio-β-D-glucopyranurono-6,1-thiolacton, 1) ether. Diazomethan-Lsg. in Me., 2) Acetylieren;

upstream raw materials:

methylthiol

1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester