Cyclohexanecarboxaldehyde, 2-methyl-4-oxo-, cis- (9CI)

Base Information

• Chemical Name: Cyclohexanecarboxaldehyde, 2-methyl-4-oxo-, cis- (9CI)
• CAS No.: 122571-34-0
• Molecular Formula: C₈H₁₂O₂
• Molecular Weight: 140.182
• Mol file: 122571-34-0.mol

Synonyms:Cyclohexanecarboxaldehyde, 2-methyl-4-oxo-, cis- (9CI)

Chemical Property of Cyclohexanecarboxaldehyde, 2-methyl-4-oxo-, cis- (9CI)

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclohexanecarboxaldehyde, 2-methyl-4-oxo-, cis- (9CI)

There total 3 articles about Cyclohexanecarboxaldehyde, 2-methyl-4-oxo-, cis- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-Crotonaldehyde (123-73-9,4170-30-3) + 2-trimethylsilyloxy-1,3-butadiene (38053-91-7) → 6-methylcyclohexa-1,3-diene-1-carbaldehyde (4748-86-1) + 1-formyl-2-methyl-4-oxocyclohexane, trans isomer (122571-30-6,122571-34-0)

Guidance literature:

With hydrogenchloride; hydroquinone; dihydroquinine; Yield given. Multistep reaction. Yields of byproduct given; 1) 150 deg C, 7 h, sealed tube, 2) reflux, 1 h;

Reference yield:

2-(trimethylsilyloxy)-1,3-pentadiene (81658-42-6) + acrolein (107-02-8,25068-14-8) → 1-formyl-2-methyl-4-oxocyclohexane, trans isomer (122571-30-6,122571-34-0) + 1-formyl-2-methyl-4-oxocyclohexane, cis isomer (122571-30-6,122571-34-0)

Guidance literature:

With methanol; hydroquinone; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1) 130 deg C, 7 h, 2) room temperature, 24 h;

Reference yield:

2-(trimethylsilyloxy)-1,3-pentadiene (81658-42-6) + acrolein (107-02-8,25068-14-8) → 1-formyl-2-methyl-4-oxocyclohexane, trans isomer (122571-30-6,122571-34-0) + 1-formyl-2-methyl-4-oxocyclohexane, cis isomer (122571-30-6,122571-34-0)

Guidance literature:

With methanol; hydroquinone; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1) 130 deg C, 7 h, 2) room temperature, 24 h;

upstream raw materials:

trans-Crotonaldehyde

2-trimethylsilyloxy-1,3-butadiene

2-(trimethylsilyloxy)-1,3-pentadiene

acrolein

Refernces