p-methoxyphenyl(phenyl)iodonium tetrafluoroborate

Base Information

• Chemical Name: p-methoxyphenyl(phenyl)iodonium tetrafluoroborate
• CAS No.: 733-53-9
• Molecular Formula: BF₄*C₁₃H₁₂IO
• Molecular Weight: 397.947
• Mol file: 733-53-9.mol

Synonyms:p-methoxyphenyl(phenyl)iodonium tetrafluoroborate

Chemical Property of p-methoxyphenyl(phenyl)iodonium tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-methoxyphenyl(phenyl)iodonium tetrafluoroborate

There total 5 articles about p-methoxyphenyl(phenyl)iodonium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

iodobenzene (591-50-4) + 4-methoxyphenylboronic acid (5720-07-0) → p-methoxyphenyl(phenyl)iodonium tetrafluoroborate (733-53-9)

Guidance literature:

iodobenzene; With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 0.5h;

4-methoxyphenylboronic acid; In dichloromethane; at 20 ℃; for 0.25h; Further stages.;

DOI:10.1021/jo8004974

Reference yield: 51.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + boron trifluoride diethyl etherate (109-63-7) + 4-methoxyphenylboronic acid (5720-07-0) → p-methoxyphenyl(phenyl)iodonium tetrafluoroborate (733-53-9)

Guidance literature:

boron trifluoride diethyl etherate; 4-methoxyphenylboronic acid; In dichloromethane; at 0 ℃; for 0.166667h; Cooling with ice;

[bis(acetoxy)iodo]benzene; In dichloromethane; at 0 - 20 ℃;

DOI:10.1016/j.jfluchem.2019.04.004

Reference yield: 49.0%

iodosylbenzene (536-80-1) + methoxybenzene (100-66-3) → p-methoxyphenyl(phenyl)iodonium tetrafluoroborate (733-53-9)

Guidance literature:

With sodium tetrafluoroborate; sulfur trioxide; In dichloromethane; 1.) -50 deg C to 20 deg C, 1 h, 2.) 20 deg C, 1.5 h;

DOI:10.1055/s-1995-4005

upstream raw materials:

iodosylbenzene

methoxybenzene

1-(diacetoxyiodo)-4-methylbenzene

iodobenzene

Downstream raw materials:

N-(4-methoxyphenyl)phenylamine

1-(4-methoxy-phenyl)-3-phenyl-propynone

1-(4-methoxyphenyl)hept-2-yn-1-one

methyl 4-methoxybenzoate

Refernces

• 1、 Hartmann, Marcel,Li, Yi,Mück-Lichtenfeld, Christian,Studer, Armido. "Generation of Aryl Radicals through Reduction of Hypervalent Iodine(III) Compounds with TEMPONa: Radical Alkene Oxyarylation". supporting information. p. 3485 - 3490. Retrieved 2016/03/05.
• 2、 Bielawski, Marcin,Aili, David,Olofsson, Berit. "Regiospecific one-pot synthesis of diaryliodonium tetrafluoroborates from arylboronic acids and aryl iodides". . p. 4602 - 4607. Retrieved 2008/09/20.