Technology Process of Zn2((MeO(CH2CH2O)3C6H4)2(NC5H4)C20H8N2C4C20H8N4(C5H4N)(C6H4(OCH2CH2)3OMe)2)
There total 2 articles about Zn2((MeO(CH2CH2O)3C6H4)2(NC5H4)C20H8N2C4C20H8N4(C5H4N)(C6H4(OCH2CH2)3OMe)2) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C96H92Br2N8O16Zn2;
bis-triphenylphosphine-palladium(II) chloride;
In
tetrahydrofuran; 1,2-dimethoxyethane;
at 20 ℃;
for 0.25h;
4-pyridylboronic acid;
With
sodium hydrogencarbonate;
In
tetrahydrofuran; 1,2-dimethoxyethane; water;
at 20 - 70 ℃;
- Guidance literature:
-
With
sodium hydrogencarbonate;
bis-triphenylphosphine-palladium(II) chloride;
In
tetrahydrofuran; 1,2-dimethoxyethane; water;
(Ar); stirring. mixt. of porphyrin deriv. and palladium compd. in DME and THF at room temp. for 15 min, addn. of boronic acid deriv., NaHCO3, water and THF, heating at 70°C overnight; cooling, filtration through celite with THF, chromy. (CH2Cl2/methanol/pyridine (97.5:2.5:1)), ppn. by layering DME soln. with pentane, NMR and MALDI;
DOI:10.1039/b814789b
- Guidance literature:
-
In
N,N-dimethyl-formamide;
at 40 ℃;
