Butanedioic acid, (bromomethyl)-, diethyl ester (9CI)

Base Information

• Chemical Name: Butanedioic acid, (bromomethyl)-, diethyl ester (9CI)
• CAS No.: 121223-90-3
• Molecular Formula: C₉H₁₅BrO₄
• Molecular Weight: 267.12
• Mol file: 121223-90-3.mol

Synonyms:Butanedioicacid, (bromomethyl)-, diethyl ester (9CI); Diethyl (bromomethyl)succinate

Chemical Property of Butanedioic acid, (bromomethyl)-, diethyl ester (9CI)

Chemical Property:

• Boiling Point: 104 - 106 °C (1.3 mmHg)
• PSA: 52.60000
• LogP: 1.51380

Purity/Quality:

Diethyl2-(bromomethyl)succinate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Butanedioic acid, (bromomethyl)-, diethyl ester (9CI)

There total 5 articles about Butanedioic acid, (bromomethyl)-, diethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methoxy-2-methyl-succinic acid (15810-05-6) → diethyl bromomethylsuccinate (121223-90-3)

Guidance literature:

With hydrogen bromide; at 150 ℃; Beim Loesen des Reaktionsprodukts in absol. Aethanol und Einleiten von HBr;

Reference yield:

ethanol (64-17-5) + bromomethyl-succinic acid (20469-57-2) → diethyl bromomethylsuccinate (121223-90-3)

Guidance literature:

With hydrogen bromide;

Reference yield:

2-methylenesuccinic acid (97-65-4,25119-64-6) → diethyl bromomethylsuccinate (121223-90-3)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrobromic acid / 160 °C

2: 110 °C

With hydrogen bromide;

upstream raw materials:

ethanol

2-methylenesuccinic acid

bromomethyl-succinic acid

2-methoxy-2-methyl-succinic acid